Benzenesulfonic acid

CAS Number
98-11-3
EC Number
202-638-7

What is Benzenesulfonic acid?

Benzenesulfonic acid (CAS 98-11-3), also known as phenylsulfonic acid, is a strong aromatic sulfonic acid used industrially as a catalyst, pH regulator, and intermediate in the synthesis of dyes, pigments, and surface-active agents.

Where is Benzenesulfonic acid used?

  • Dye and pigment manufacturing: sulfonation intermediate and coupling agent
  • Textile and leather processing: pH control during dyeing and tanning
  • Coatings and resins: acid catalyst for curing in baking enamels and crosslinked polymer formulations
  • Printing inks: dispersing aid that stabilizes pigment suspensions and improves press flow
  • It influences color yield and batch consistency during production.

Commercial specifications

  • Aqueous solution, most commonly 65–70%
  • Higher-purity grades for catalyst and specialty applications, with consistent acid content and low impurity profiles

Other Names (Synonyms)

Phenylsulfonic acid|Besylic acid|Benzenemonosulfonic acid|Benzene sulphonic acid|Kyselina benzensulfonova|17-120A

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What are the physical properties of Benzenesulfonic acid?

Melting Point 65 °C
Boiling Point 137°C
Density 1.32
Flash Point >230 °F
Appearance green solid
Color Yellow to light brown
Form Damp Crystalline Solid or Fused Mass
Water Solubility soluble
Vapor Pressure 69.8Pa at 20℃
Refractive Index 1.5151 (estimate)
pH 2 (H2O, 20℃)(saturated solution)
Log P 0.41 at 25℃

How is Benzenesulfonic acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Benzenesulfonic acid?

HS Code 29041000
UN Number 2583
ADR Class 8
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 1
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