Benzenesulfonyl chloride

CAS Number
98-09-9
EC Number
202-636-6

What is Benzenesulfonyl chloride?

Benzenesulfonyl chloride (CAS 98-09-9), also known as phenylsulfonyl chloride, is a reactive sulfonylating agent.

Where is Benzenesulfonyl chloride used?

  • Pharmaceutical manufacturing: key building block for sulfonamide drugs, protecting groups and active pharmaceutical intermediates requiring controlled sulfonylation
  • Dye and pigment production: manufacture of azo dyes for textile and leather finishing
  • Water treatment: sulfonyl chloride-derived compounds as biocidal actives targeting microbial control
  • Paper processing: sulfonyl-based surface treatment agents that improve wet strength and resistance properties
  • It introduces sulfonyl groups into organic molecules, enabling construction of intermediates.

Good to know: Sensitive to hydrolysis during storage and transit; buyers should confirm moisture-controlled packaging requirements with suppliers.

Commercial specifications

  • Technical grade and high-purity grades
  • Purity typically confirmed by GC analysis
  • Standard drum and IBC packaging

Other Names (Synonyms)

Phenylsulfonyl chloride|Benzene sulfochloride|Benzenesulfonic chloride|Benzene sulfonechloride|Benzenesulphonyl chloride

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What are the physical properties of Benzenesulfonyl chloride?

Melting Point 14.5 °C
Boiling Point 120 °C @ Press: 10 Torr
Density 1.3842 g/cm³ @ Temp: 15 °C
Flash Point >230 °F
Appearance Benzenesulfonyl chloride is a colorless oily liquid with a pungent odor.
Color Clear
Form Liquid
Water Solubility may decompose
Vapor Pressure 0.04 mm Hg ( 20 °C)
Refractive Index n 20/D 1.551(lit.)
Log P 3.39 at 23℃

How is Benzenesulfonyl chloride classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Benzenesulfonyl chloride?

HS Code 29049090
UN Number 2225
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 1
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