4-hydroxybenzenesulfonic acid

CAS Number
98-67-9
EC Number
202-691-6

What is 4-hydroxybenzenesulfonic acid?

4-Hydroxybenzenesulfonic acid (CAS 98-67-9), also known as phenolsulfonic acid or sulfocarbolic acid, is an aromatic sulfonic acid used in industrial processing and formulation chemistry.

Where is 4-hydroxybenzenesulfonic acid used?

  • Textile dyeing and leather tanning: fixative and pH regulator improving dye uptake
  • Printing ink and packaging coatings: stabilizes pigment dispersions and extends shelf life against UV degradation
  • Personal care: supports preservation systems and UV stabilization
  • Paper treatment: buffering agent controlling acidity during pulp processing and surface sizing
  • It functions as a pH buffer, UV stabilizer, and preservation agent in manufacturing workflows.

Good to know: Purity specifications may vary depending on application requirements.

Commercial specifications

  • Aqueous solution, 65–70% concentration

Other Names (Synonyms)

Sulfocarbolic acid|Phenolsulfonic acid|p-Sulfophenol|p-Hydroxybenzenesulfonic acid|Hydroxybenzene-4-sulfonic acid|4-Sulfophenol|p-Phenolsulfonic acid|4-Phenolsulfonic acid

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What are the physical properties of 4-hydroxybenzenesulfonic acid?

Melting Point 52 °C
Boiling Point 275.14°C (rough estimate)
Density 1.337 g/cm³
Appearance yellowish oily liquid
Color White to Light yellow to Light red
Form Liquid
Water Solubility Soluble in water.
Vapor Pressure 69.8Pa at 20℃
Refractive Index n 20/D 1.489
Log P 0.41 at 25℃

How is 4-hydroxybenzenesulfonic acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to 4-hydroxybenzenesulfonic acid?

HS Code 29089990
UN Number 2586
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
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