4-hydroxybenzenesulfonic acid

CAS Number
98-67-9
EC Number
202-691-6
Chemical Formula
C6H6O4S
Molecular Weight
174.18 g/mol

Description

4-Hydroxybenzenesulfonic acid (CAS 98-67-9), also known as phenolsulfonic acid or sulfocarbolic acid, is an aromatic sulfonic acid used across industrial processing and formulation chemistry. It functions primarily as a pH buffer, UV stabilizer, and preservation agent in manufacturing workflows where precise acidity control and oxidative stability are required for the final product.

In textile dyeing and leather tanning, it acts as a fixative and pH regulator, improving dye uptake and process consistency across batch production cycles and large scale industrial operations. Printing ink and packaging coating formulators incorporate it to stabilize pigment dispersions and extend shelf life against UV-induced degradation in various environmental conditions.

In personal care formulations, it supports preservation systems and contributes to UV stabilization in products where phenolic-based protection is commercially preferred by manufacturers. Paper treatment processes use it as a buffering agent to control acidity during pulp processing and surface sizing, ensuring the structural integrity and quality of the finished paper goods.

This chemical is supplied as an aqueous solution, with 65–70% concentration being the most commonly traded commercial form for global distribution and bulk industrial procurement. Technical grade is the standard offering for industrial applications in textiles, printing, and leather processing. Purity specifications may vary depending on specific application requirements.

Other Names (Synonyms)

Sulfocarbolic acid|Phenolsulfonic acid|p-Sulfophenol|p-Hydroxybenzenesulfonic acid|Hydroxybenzene-4-sulfonic acid|4-Sulfophenol|p-Phenolsulfonic acid|4-Phenolsulfonic acid

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 52 °C
Boiling Point 275.14°C (rough estimate)
Density 1.337 g/cm³
Appearance yellowish oily liquid
Color White to Light yellow to Light red
Form Liquid
Water Solubility Soluble in water.
Vapor Pressure 69.8Pa at 20℃
Refractive Index n 20/D 1.489
Log P 0.41 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29089990
UN Number 2586
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
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