Styrene

CAS Number
100-42-5
EC Number
202-851-5

What is Styrene?

Styrene (CAS 100-42-5), also known as vinylbenzene, is a reactive liquid monomer that forms the chemical backbone of synthetic polymers and resins.

Where is Styrene used?

  • Polystyrene and EPS: rigid packaging, insulation board, disposable foodservice items
  • Coatings and adhesives: copolymerises with acrylates or butadiene for binders with controlled hardness
  • SBR and latex systems: core monomer for sealants, carpet backing, pressure-sensitive adhesives
  • At food-grade purity it serves as a flavoring ingredient in approved formulations.
  • Used in the manufacture of abrasive products, precast concrete and cement elements, artificial stone, and lightweight, expanded and blown conglomerate elements.
  • Used in the manufacture and repair of metal vehicle bodies and in civil and industrial plant engineering.
  • Used to produce unsaturated polyester resins for coatings.
  • Forms copolymers such as styrene-acrylonitrile (SAN) and styrene-acrylonitrile-butadiene (ABS), used to make pipes, automotive parts and plastic lenses.

Good to know: At trace levels it carries FEMA 3233 status as a recognized flavoring agent. Inhibited with 4-tert-butylcatechol (TBC) to prevent premature polymerization during storage and transit.

Formulation notes

  • FES resins (low styrene emission) contain adjuvants incompatible with the resin that form a barrier film on the surface, limiting styrene emissions during static phases (polymerization) but not during spraying phases.

Regulatory status

  • The IARC classifies styrene as a probable human carcinogen.
  • Classified as a flammable liquid and vapour under CLP.
  • Classified as suspected of damaging the unborn child under CLP.

Storage, packaging and handling

  • Concentrations in air between 0.9% and 6.8% create an explosion risk.
  • Drying of styrene-containing parts should be carried out in a ventilated room, preferably separate.

Frequently asked questions about Styrene

What regulatory classification applies to styrene for hearing effects in the EU?
Styrene is classified as causing proven serious effects on hearing organs (H372) under the European regulation applicable from 1 January 2016.
Is styrene authorised for food-contact applications in the European Union?
In the European Union, styrene is authorised for use in food packaging intended for direct contact with food.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

Vinyl-Benzene|Styrolene|styrol|styrene monomer|Phenyl-Ethylene|Ethenylbenzene, 9CI|Ethenyl-Benzene|Cinnamol

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What are the physical properties of Styrene?

Melting Point -31 °C
Boiling Point 145 °C
Density 0.9060 g/cm³ @ Temp: 20 °C
Flash Point 88 °F
Appearance Styrene is a colorless to yellowish, very refractive, oily liquid with a penetrating odor
Color Colorless
Odor at 0.10 % in triacetin. sweet balsam floral plastic
Form Liquid
Water Solubility 0.3 g/L (20 ºC)
Vapor Pressure 12.4 mm Hg ( 37.7 °C)
Refractive Index n 20/D 1.546(lit.)
Log P 2.96 at 25℃

How is Styrene classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H226 Flammable liquid and vapor
H303 May be harmful if swallowed
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Styrene?

HS Code 29025000
UN Number 2055
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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