alpha-methylstyrene

CAS Number
98-83-9
EC Number
202-705-0
Abbreviation
AMS

What is alpha-methylstyrene?

Alpha-methylstyrene (CAS 98-83-9), commonly abbreviated as AMS, is a reactive monomer and co-monomer used in polymer chemistry and specialty chemical manufacturing. Also known as isopropenyl benzene.

Where is alpha-methylstyrene used?

  • Resin synthesis: building block and chain-transfer agent or modifier
  • Coatings and adhesives: incorporated into styrene-acrylic and alkyd resin formulations to improve hardness, heat resistance and film build
  • Packaging materials and printing inks: co-monomer in AMS-modified resins where controlled molecular weight is a production requirement
  • Elastomer and sealant compounding: tackifiers and performance modifiers
  • At trace levels it is approved as a flavoring agent under FEMA guidelines.

Good to know: Inhibited grades prevent premature polymerization during storage and transport. Not to be confused with isopropenyl benzene, a recognized alternative name in some technical contexts.

Commercial specifications

  • Purity: 99% to 99.5%+ depending on end-use requirements
  • Clear liquid in bulk, ISO tank and drum quantities

Other Names (Synonyms)

α-methylstyrene|isopropyl benzene|Isopropenyl benzene|2-Phenylpropene|2-phenyl propylene|1-methyl-1-phenylethylene|AMS|2-Phenyl-1-propene

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What are the physical properties of alpha-methylstyrene?

Melting Point -23.2 °C
Boiling Point 165.4 °C
Density 0.9106 g/cm³
Flash Point 114 °F
Appearance Methylstyrene is a colorless liquid with a characteristic odor.
Color Clear colorless
Form Liquid
Water Solubility insoluble
Vapor Pressure 2.1 mm Hg ( 20 °C)
Refractive Index n 20/D 1.539
pH 5-6 (500g/l, H2O)
Log P 3.48 at 25℃

How is alpha-methylstyrene classified and handled safely? Learn More

Warning
GHS02· Flammable GHS07· Irritant GHS09· Environmental Hazard GHS05· Corrosive GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H303 May be harmful if swallowed
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to alpha-methylstyrene?

HS Code 29029090
UN Number 2303
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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