Bismuth trioxide

CAS Number
1304-76-3
EC Number
215-134-7
Abbreviation
Bi2O3

What is Bismuth trioxide?

Bismuth trioxide (CAS 1304-76-3), also referenced by the formula Bi2O3, is an inorganic bismuth compound used as a functional additive and raw material in electronics manufacturing and specialty materials production.

Where is Bismuth trioxide used?

  • Electronics: oxide source in low-temperature co-fired ceramics (LTCC), varistors and dielectric formulations, lowering sintering temperatures and modifying electrical properties
  • Specialty glass: radiation-shielding and optical glass with elevated density and refractive characteristics, substituting for lead oxide
  • Printing and packaging: yellow-to-orange inorganic pigment in ceramic inks and decorative coatings on glass and ceramic substrates
  • Flux compositions and soldering materials: bismuth oxide source with defined purity
  • It also serves as an oxide source where controlled melting behavior, high refractive index contribution or dense inorganic pigmentation is required.

Commercial specifications

  • Fine yellow powder in varying particle size distributions
  • Technical and high-purity grades; ultra-high purity grades for electronic and optical applications requiring ACS or USP compliance
  • Packaging from kilogram-scale bags to bulk quantities

Other Names (Synonyms)

Bismuth(iii) oxide|Bismuth oxide (Bi2O3)|Oxo(oxobismuthanyloxy)bismuthane|Bismuth oxide|Bi2O3

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What are the physical properties of Bismuth trioxide?

Melting Point 820 °C
Boiling Point 1980 °C
Density 9.37 g/cm³ (solid)
Flash Point 1890°C
Appearance Heavy, Yellow Powder
Color Yellow
Odor Odorless
Form powder
Water Solubility INSOLUBLE

How is Bismuth trioxide classified and handled safely? Learn More

Danger
GHS08· Health Hazard

Hazard Statements

H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P319 Get medical advice/attention if you feel unwell.

Which trade and regulatory codes apply to Bismuth trioxide?

HS Code 28259021
Storage Class 11 - Combustible Solids
WGK (Germany) 2
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