Antimony trioxide

CAS Number
1309-64-4
EC Number
215-175-0

What is Antimony trioxide?

Antimony trioxide (CAS 1309-64-4), also known as Flowers of Antimony, is a flame retardant synergist used in plastics, textiles, and industrial materials.

Where is Antimony trioxide used?

  • Plastics and polymers: compounded with brominated or chlorinated flame retardants to meet UL 94 and other flammability standards in wire insulation, connectors, and housings
  • Textile and fabric coatings: automotive interiors, upholstery, and protective workwear
  • Construction materials: PVC profiles, roofing membranes, and wall panels where building codes mandate flame resistance
  • Electronics: printed circuit board laminates and encapsulant compounds to control flame spread in high-density assemblies
  • It amplifies the performance of halogenated flame retardant systems, allowing formulators to achieve target fire ratings at lower total additive loadings.
  • In the absence of antimony trioxide, about twice as much halogenated compound would be needed to achieve the same level of flame retardancy.
  • Used as a catalyst in PET production.
  • Used as a clarifying aid in glasses.
  • Used as an opacifier in cast iron and dip enameling baths.

Good to know: It does not act as a standalone flame retardant.

Formulation notes

  • In PET preparation, the amount used may range from 100-300 mg/kg.
  • Reacts violently with bromine trifluoride.
  • Reacts with hydrogen under certain conditions to produce stibine, a very toxic gas.

Typical specification

  • A wetted grade is available with plasticizers, typically 4% DIDP.
  • Available in a Standard Grade with 99.5% purity.

Regulatory status

  • Not regulated for transport under special provision SP45 unless it contains more than 0.5% arsenic.
  • The harmonised classification and labelling index number under the EU CLP Regulation is 051-005-00-X.

Frequently asked questions about Antimony trioxide

In which applications is antimony trioxide used as a pigment?
Antimony trioxide is used as a paint pigment.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

Flowers of Antimony|Antimony(III) oxide|Antimony sesquioxide|Antimonous oxide|Diantimony trioxide|Antimonious oxide|Exitelite|Timonox

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What are the physical properties of Antimony trioxide?

Melting Point 655 °C
Boiling Point 1425 °C
Density 5.2 g/cm³ (solid)
Flash Point 1550°C subl.
Appearance White or gray mineral, sometimes pale red, white streak and adamantine or silky luster. Mohs hardness 2–3.
Color White
Odor wh. cubic or orthorhombic cryst., odorless
Form powder
Water Solubility Slightly soluble. <0.1 g/100 mL at 20 ºC
Vapor Pressure 13.3 hPa (660 °C)

How is Antimony trioxide classified and handled safely? Learn More

Warning
GHS08· Health Hazard GHS09· Environmental Hazard GHS07· Irritant

Hazard Statements

H351 Suspected of causing cancer [Warning Carcinogenicity]
H350 May cause cancer [Danger Carcinogenicity]
H401 Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard]
H411 Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

Which trade and regulatory codes apply to Antimony trioxide?

HS Code 28258000
Storage Class 13 - Non Combustible Solids
WGK (Germany) 2
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