Lead monoxide

CAS Number
1317-36-8
EC Number
215-267-0

What is Lead monoxide?

Lead monoxide (CAS 1317-36-8), known as litharge or massicot depending on its crystalline form, is an inorganic lead compound used as a reactive oxide in industrial processing.

Where is Lead monoxide used?

  • Rubber and tire production: vulcanization activator and accelerator co-agent, improving cross-link density and heat resistance in specialty compounds
  • Metallurgical processing: flux in lead refining and smelting operations
  • In smelting it facilitates the separation of impurities from base metal melts.
  • Glass manufacturing: precursor in lead-based glass formulations, contributing to refractive index and density in optical and crystal glass
  • Mining and metals processing: intermediate in the recovery and refining of lead from ore concentrates

Good to know: Both litharge (alpha-PbO) and massicot (beta-PbO) polymorphic forms are available, with litharge being the predominant commercial form.

Commercial specifications

  • Particle size and purity specifications vary by end-use requirement
  • Technical and industrial purity levels, typically at 99% minimum lead oxide content

Other Names (Synonyms)

Lead(ii) oxide|Lead oxide (pbo)|Oxolead|Lead oxide

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What are the physical properties of Lead monoxide?

Melting Point 888 °C
Boiling Point 1470 °C
Density 9.53 g/cm³
Appearance light yellow-orange powder
Color yellow
Form powder
Water Solubility Soluble in concentrated alkali, hydrochloric acid, and ammonium chloride. Insoluble in water, dilute alkali and alcohol.
Vapor Pressure 10 mm Hg ( 0 °C)
Refractive Index 2.67
pH 8-9 (100g/l, H2O, 20℃)(slurry)

How is Lead monoxide classified and handled safely? Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H302 Harmful if swallowed
H316 Causes mild skin irritation
H332 Harmful if inhaled
H341 Suspected of causing genetic defects

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P263 Avoid contact during pregnancy and while nursing.

Which trade and regulatory codes apply to Lead monoxide?

HS Code 28241000
UN Number 2291
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3
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