Sodium methallylsulfonate

CAS Number
1561-92-8
EC Number
216-341-5
Chemical Formula
C4H8O3S.Na
Molecular Weight
158.15 g/mol
Abbreviation
SMAS

Description

Sodium methallylsulfonate (CAS 1561-92-8), commonly abbreviated as SMAS, is a reactive sulfonate monomer used as a functional comonomer in polymer synthesis. It introduces anionic sulfonate groups into polymer backbones. This chemical enables targeted performance modifications in industrial formulations. In water treatment, SMAS is copolymerized into scale inhibitors and dispersants that prevent mineral deposition in cooling towers.

These industrial water systems benefit from the enhanced stability provided by the monomer. Textile and paper processing operations use SMAS-based polymers to improve dye uptake and fiber affinity. The monomer also improves surface sizing performance in paper manufacturing. In the plastics and polymers sector, it is incorporated into acrylic and vinyl copolymers to enhance colloidal stability.

This improves electrolyte tolerance in emulsion systems during production. Leather processing also employs SMAS-derived polymers as retanning and dispersing agents for better results. These agents improve the penetration and uniformity of treatment across the material. Sodium methallylsulfonate is typically supplied as a white crystalline powder or as an aqueous solution.

Standard concentrations are available, and the Technical grade is the primary commercial specification for industrial buyers. It is offered in bulk quantities suited to polymer manufacturing. Packaging options range from bags to intermediate bulk containers to meet logistics needs. This versatile monomer remains a critical component for high-performance anionic polymer production.

Other Names (Synonyms)

Methallyl sulfonate|Sodium 2-methylprop-2-ene-1-sulphonate|ARA0T9ZU4A|RefChem:156852|sodium methylallyl sulfonate|Sodium 2-methylprop-2-ene-1-sulfonate|2-Propene-1-sulfonic acid, 2-methyl-, sodium salt (1:1)|SMAS

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point >300 °C(lit.)
Density 1.59[at 20℃]
Color White to Almost white
Form powder to crystal
Water Solubility 523g/L at 20℃
Vapor Pressure 0Pa at 20℃
Log P -3.74 at 20℃

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.

Trade & Regulatory

HS Code 2904.10.5000
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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