Bis(2-(methacryloyloxy)ethyl) phosphate

CAS Number
32435-46-4
EC Number
251-040-2

What is Bis(2-(methacryloyloxy)ethyl) phosphate?

Bis(2-(methacryloyloxy)ethyl) phosphate (CAS 32435-46-4) is a bifunctional phosphate monomer combining a reactive methacrylate group with a pendant phosphate moiety. Also known as bis(methacryloyloxyethyl) hydrogen phosphate.

Where is Bis(2-(methacryloyloxy)ethyl) phosphate used?

  • UV- and thermally-cured coatings: reactive flame-retardant monomer bound into the polymer network
  • Adhesives and sealants: improved bonding to metal and mineral substrates
  • Printing inks and packaging coatings: substrate wetting and anchorage on aluminum foil and treated films
  • Polymer compounders use it as a co-monomer to introduce inherent flame retardancy into acrylic systems.

Good to know: The phosphate group coordinates with surface oxides to enhance adhesion without a separate primer layer. The phosphate functionality delivers flame retardancy and surface adhesion promotion within a polymerizable matrix, eliminating separate additive packages and preventing plasticizer-style migration losses.

Commercial specifications

  • Purity confirmed by acid value and phosphorus content assays
  • Packaging from small R&D quantities to bulk drums

Other Names (Synonyms)

Bis(methacryloyloxyethyl) hydrogen phosphate|bis(2-methacryloyloxyethyl) hydrogen phosphate|2-Propenoic acid, 2-methyl-, phosphinicobis(oxy-2,1-ethanediyl) ester|2-Propenoic acid, 2-methyl-, 1,1′-[phosphinicobis(oxy-2,1-ethanediyl)] ester|Methacrylic acid, 2-hydroxyethyl ester, hydrogen phosphate|2-Hydroxyethyl methacrylate phosphate (2:1)|BIS(METHACRYLOYLOXYETHYL) PHOSPHATE

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What are the physical properties of Bis(2-(methacryloyloxy)ethyl) phosphate?

Boiling Point 221 °C(lit.)
Density 1.28 g/mL at 25 °C(lit.)
Flash Point >230 °F
Refractive Index n 20/D 1.47(lit.)

How is Bis(2-(methacryloyloxy)ethyl) phosphate classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.

Which trade and regulatory codes apply to Bis(2-(methacryloyloxy)ethyl) phosphate?

HS Code 29199000
Storage Class 10 - Combustible liquids
WGK (Germany) 3
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