Dimethylolpropionic acid

CAS Number
4767-03-7
EC Number
225-306-3
Abbreviation
DMPA

What is Dimethylolpropionic acid?

Dimethylolpropionic acid (CAS 4767-03-7), commonly known as DMPA, is a bifunctional monomer carrying both hydroxyl and carboxylic acid groups.

Where is Dimethylolpropionic acid used?

  • Waterborne polyurethane dispersions: internal emulsifier, carboxylic acid group neutralized
  • Wood, leather and plastic coatings: stable, solvent-free
  • Adhesives and sealants: in polyurethane prepolymers for crosslink density and substrate adhesion
  • Polyester and alkyd resins: chain extender improving water compatibility for industrial and architectural coatings
  • Personal care: film-forming agents in hair fixatives and skin-feel modifiers
  • It introduces ionic or hydrophilic character into polyurethane and polyester systems.

Good to know: This structure enables water dispersibility without external emulsifiers.

Commercial specifications

  • Purity 98% and above
  • Technical and high-purity variants
  • 25 kg bags
  • Bulk quantities for industrial procurement

Other Names (Synonyms)

2,2-Bis(hydroxymethyl)propionic acid|3-Hydroxy-2-(hydroxymethyl)-2-methylpropanoic acid|2,2-Bis(hydroxymethyl)propanoic acid|DIHYDROXYPIVALIC ACID|.alpha.,.alpha.-Dimethylolpropionic acid|Propanoic acid, 3-hydroxy-2-(hydroxymethyl)-2-methyl-|Propionic acid, 2,2-bis(hydroxymethyl)-|DMPA

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What are the physical properties of Dimethylolpropionic acid?

Melting Point 190 °C
Boiling Point 167.23°C (rough estimate)
Density 0.84
Flash Point >150°C
Appearance white crystalline powder
Color White
Form Crystalline Powder
Water Solubility soluble
Refractive Index 1.4240 (estimate)
pH 2.6 (50g/l, H2O, 20℃)

How is Dimethylolpropionic acid classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P319 Get medical advice/attention if you feel unwell.

Which trade and regulatory codes apply to Dimethylolpropionic acid?

HS Code 29159000
WGK (Germany) 3
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