Octamethylcyclotetrasiloxane

CAS Number
556-67-2
EC Number
209-136-7
Abbreviation
D4

What is Octamethylcyclotetrasiloxane?

Octamethylcyclotetrasiloxane (CAS 556-67-2), commonly abbreviated as D4, is a cyclic siloxane monomer used as a key building block in silicone polymer synthesis.

Where is Octamethylcyclotetrasiloxane used?

  • Coatings: reactive intermediate and processing aid
  • Personal care: carrier and emollient base in hair conditioners and skin creams
  • Polymer manufacturing: reactive intermediate and processing aid
  • In silicone elastomer and sealant production, D4 undergoes ring-opening polymerization to produce polydimethylsiloxane chains of controlled molecular weight.
  • Industrial coatings and release liners: surface modifier and crosslinking precursor, improving substrate wetting and film durability
  • Adhesive and sealant manufacturing: reactive diluent to control viscosity and cure behavior in silicone formulations

Good to know: D4 is subject to concentration restrictions in certain jurisdictions, requiring careful formulation and adherence to local safety standards. Buyers should confirm regulatory compliance status for their target market, particularly for personal care applications.

Commercial specifications

  • Purity typically 99% or higher
  • Drum and IBC quantities
  • Bulk tanker options for high-volume requirements

Other Names (Synonyms)

cyclic dimethylsiloxane tetramer|2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetroxatetrasilocane|2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane|cyclomethicone 4|Cyclotetrasiloxane, octamethyl-|OMCTS|NUC silicone VS 7207|Union carbide 7207|D4

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What are the physical properties of Octamethylcyclotetrasiloxane?

Melting Point 17.5 °C
Boiling Point 175 °C
Density 0.9558 g/cm³
Flash Point 140 °F
Appearance Colorless clear liquid
Color colorless
Form liquid
Water Solubility INSOLUBLE
Vapor Pressure 1.32hPa at 25℃
Refractive Index n 20/D 1.396(lit.)
Log P 6.98 at 21.7℃

How is Octamethylcyclotetrasiloxane classified and handled safely? Learn More

Warning
GHS08· Health Hazard GHS09· Environmental Hazard GHS02· Flammable

Hazard Statements

H226 Flammable liquid and vapor
H361 Suspected of damaging fertility or the unborn child
H410 Very toxic to aquatic life with long lasting effects
H413 May cause long lasting harmful effects to aquatic life

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Octamethylcyclotetrasiloxane?

HS Code 29319090
UN Number 1993
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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