Dimethylamine borane

CAS Number
74-94-2
EC Number
200-823-7
Abbreviation
DMAB

What is Dimethylamine borane?

Dimethylamine borane (CAS 74-94-2), commonly abbreviated as DMAB, is a stable borane complex used industrially as a selective reducing agent and electroless plating initiator.

Where is Dimethylamine borane used?

  • Electroless nickel and cobalt plating: reducing agent that drives metal deposition onto non-conductive substrates, including plastics and printed circuit boards
  • Electronics: metallization steps where deposit quality and bath stability are procurement considerations
  • Pharmaceutical and fine chemical synthesis: reductive amination and selective carbonyl reduction where sodium borohydride would be too aggressive for the solvent system
  • Specialty polymer and adhesive formulations: curing initiator
  • It serves as a milder, more manageable alternative to sodium borohydride in industrial chemical synthesis.

Good to know: Controlled reactivity makes it a preferred alternative to sodium borohydride where milder reduction conditions are needed. High-purity grades are available for pharmaceutical synthesis and electronics.

Commercial specifications

  • Packaged under inert conditions to preserve stability during storage and transit
  • Bulk quantities in multi-kilogram drums for laboratory and development-scale procurement

Other Names (Synonyms)

Borane-dimethylamine complex|DMAB|Dimethylamine borane (1:1)|BKK4RT45YA|Boron, trihydro(N-methylmethanamine)-, (T-4)-|Dimethylamine compound with borane (1:1)|Dimethylamine, compd. with borane (1:1)|Methanamine, N-methyl-, compd. with borane (1:1)

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What are the physical properties of Dimethylamine borane?

Melting Point 37 °C
Boiling Point 63 °C @ Press: 1 Torr
Density 0,69 g/cm 3
Flash Point 110 °F
Appearance white crystalline powder with an amine odour
Color White to yellow
Form Flakes or Granules
Water Solubility 125 g/L (20 ºC)
Vapor Pressure <5 hPa (20 °C)
pH 8-9 (10g/l, H2O, 20℃)

How is Dimethylamine borane classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS09· Environmental Hazard

Hazard Statements

H228 Flammable solid
H301 Toxic if swallowed
H311 Toxic in contact with skin
H317 May cause an allergic skin reaction

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Which trade and regulatory codes apply to Dimethylamine borane?

HS Code 29420000
UN Number 2926
ADR Class 4.1
Packing Group II
WGK (Germany) 2
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