Stannous fluoride

CAS Number
7783-47-3
EC Number
231-999-3

What is Stannous fluoride?

Stannous fluoride (CAS 7783-47-3), also known commercially as tin difluoride, is an inorganic tin salt used primarily as an active ingredient in oral care and pharmaceutical formulations.

Where is Stannous fluoride used?

  • Toothpaste and mouth rinse: caries-prevention agent and antibacterial active targeting plaque and gingivitis at 0.4% to 0.454%
  • Pharmaceutical oral care: prescription-strength gels and professional dental treatments requiring dual fluoride and antimicrobial efficacy
  • Specialty whitening and sensitivity-relief dentifrice: stannous ion contributes to tubule occlusion and stain-blocking
  • In metal finishing it is used in some industrial surface treatment applications.

Good to know: It delivers fluoride ion activity combined with antimicrobial action, making it a distinct functional choice compared to sodium fluoride or amine fluoride systems.

Commercial specifications

  • USP and pharmaceutical-grade specifications, purity typically 98% or higher

Other Names (Synonyms)

Tin difluoride|Tin bifluoride|Tin Fluoride (SnF2)|Easygel|Stancare|Stanide|Crest|Stop

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What are the physical properties of Stannous fluoride?

Melting Point 213 °C
Boiling Point 850 °C
Density 4.57 g/cm³ @ Temp: 25 °C
Appearance Stannous fluoride is a white crystalline solid with a bitter, salty taste.
Color White to off-white
Form Powder, Crystals or Crystalline Powder
Water Solubility Soluble in potassium hydroxide and potassium fluoride. Insoluble in water, ethanol, ether and chloroform.
Log P -1.357 (est)

How is Stannous fluoride classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H300 Fatal if swallowed
H301 Toxic if swallowed
H302 Harmful if swallowed

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Stannous fluoride?

HS Code 28261990
UN Number 2923
ADR Class 8
Packing Group III
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 3
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