Allyl bromide

CAS Number
106-95-6
EC Number
203-446-6

What is Allyl bromide?

Allyl bromide (CAS 106-95-6) is a reactive alkylating agent used primarily as a chemical building block in pharmaceutical synthesis and specialty chemical manufacturing. Also known commercially as 3-bromopropene.

Where is Allyl bromide used?

  • Pharmaceutical manufacturing: key intermediate in synthesizing APIs
  • Biotechnology and life sciences: functionalizing biomolecules and synthesizing allylated nucleosides or amino acid derivatives
  • Agrochemical intermediates and specialty monomers: controlled allyl group incorporation
  • Quaternary ammonium biocides: alkylating precursor
  • It introduces the allyl group into target molecules through nucleophilic substitution reactions.

Good to know: Stabilized form prevents premature polymerization during storage. Technical and high-purity grades meet requirements of pharmaceutical intermediate synthesis and research applications.

Commercial specifications

  • Technical and high-purity grades
  • Packaging from small laboratory quantities to bulk drums
  • Batches tested to internal quality standards and customer specifications

Other Names (Synonyms)

3-bromoprop-1-ene|3-Bromopropene|3-Bromo-1-propene|1-Propene, 3-bromo-|3-Bromopropylene|2-Propenyl bromide|1-Bromo-2-propene|Propene, 3-bromo-

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What are the physical properties of Allyl bromide?

Melting Point -119 °C
Boiling Point 71.3 °C @ Press: 760 Torr
Density 1.398 g/cm³ @ Temp: 20 °C
Flash Point 28 °F
Appearance Allyl bromide is a highly flammable, colorless to light yellow liquid with an unpleasant, pungent odor.
Color Clear colorless to slightly colored
Odor unpleasant
Form Liquid
Water Solubility insoluble
Vapor Pressure 18.66kPa at 25℃
Refractive Index n 20/D 1.469(lit.)
Log P 1.79

How is Allyl bromide classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H225 Highly Flammable liquid and vapor
H300 Fatal if swallowed
H301 Toxic if swallowed
H310 Fatal in contact with skin

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Allyl bromide?

HS Code 29033036
UN Number 1099
ADR Class 3
Packing Group I
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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