1-bromohexane

CAS Number
111-25-1
EC Number
203-850-2
Chemical Formula
C6H13Br
Molecular Weight
165.07 g/mol

Description

1-Bromohexane (CAS 111-25-1), also known as hexyl bromide, is a straight-chain alkyl bromide used as a reactive intermediate in organic synthesis. It functions primarily as an alkylating agent, introducing the hexyl chain into target molecules. This versatile chemical is utilized across pharmaceutical, polymer, and specialty chemical manufacturing sectors. In pharmaceutical synthesis, it is used to N- or O-alkylate active pharmaceutical intermediates for drug development.

This process enables the construction of drug candidates with defined lipophilicity profiles. Polymer chemists use it to functionalize monomers and modify backbone structures, influencing solubility and processing behavior in specialty plastics. In the production of quaternary ammonium compounds, it reacts with tertiary amines to yield surfactants. These products serve as phase-transfer catalysts used in textile processing and various industrial formulation chemistry applications.

Fragrance and flavor manufacturers also employ it as a precursor in synthesizing hexyl esters and ethers. These derivatives are essential for creating targeted sensory profiles in consumer goods and food-grade additives. The product is supplied as a clear to pale yellow liquid in drum and IBC quantities. Smaller packaging options are available for laboratory and pilot-scale procurement to meet specific research and development requirements.

Technical grade is the standard commercial offering, with high-purity grades available to meet fine chemical specifications. Purity documentation including GC analysis and COA is standard for regulated supply chains.

Other Names (Synonyms)

hexyl bromide|n-Hexyl bromide|1-Hexyl bromide|Hexane, 1-bromo-|WVA0FAX7GA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -84.7 °C
Boiling Point 158 °C
Density 1.16 g/cm³
Flash Point 135 °F
Appearance colourless liquid
Color Clear
Form Liquid
Water Solubility Immiscible with water.
Vapor Pressure <10 mm Hg ( 20 °C)
Refractive Index n 20/D 1.448(lit.)

Documentation

Safety & Handling Learn More

Warning
GHS02· Flammable GHS07· Irritant GHS09· Environmental Hazard

Hazard Statements

H226 Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Trade & Regulatory

HS Code 29033036
UN Number 1993
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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