SoleChem

Allyl acetoacetate

CAS
1118-84-9
EC
214-269-9
Mol. Weight
142.15 g/mol

Description

Allyl acetoacetate (CAS 1118-84-9), also known as allyl acetylacetate, is a reactive ester used as a chemical intermediate and flavoring agent across pharmaceutical, cosmetic, and food industries.

Its dual functionality, combining an active methylene group with a polymerizable allyl moiety, makes it a building block for synthesis and a carrier in formulated products.

In pharmaceutical manufacturing, it serves as a synthetic intermediate for active pharmaceutical ingredients where controlled reactivity at the methylene position is required for complex synthesis.

Flavor and fragrance formulators incorporate it into compositions targeting fruity, herbaceous, or green scent profiles, particularly in fine fragrance and food flavoring applications.

Cosmetic chemists use it as a carrier and reactive component in skin-care and hair-care formulations where controlled release or film-forming properties are needed for performance.

It also functions as a crosslinking or co-monomer component in specialty polymer and resin systems, providing versatility for industrial material science and chemical engineering projects.

Allyl acetoacetate is supplied as a clear to pale yellow liquid in standard drum and IBC packaging suited to industrial procurement volumes and global logistics requirements.

Technical and reagent-grade specifications are the most commonly available, with purity levels typically at 97% or higher. Buyers should confirm compliance with relevant FEMA codes.

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Physical Properties

Melting Point -85 °C
Boiling Point 84-85 °C @ Press: 10 Torr
Density 1.0366 g/cm³ @ Temp: 25 °C
Flash Point 75 °C
Appearance clear colorless to slightly yellow liquid
Color Colorless to Light yellow to Light orange
Form clear liquid
Water Solubility 50 g/L (20 ºC)
Vapor Pressure 0.2 hPa (20 °C)
Refractive Index n 20/D 1.439(lit.)
pH 3.7 (48g/l, H2O, 20℃)
Log P 0.146 at 27℃

Safety & Handling (Learn More)

Danger GHS06 GHS07
Hazard Statements
H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
Precautionary Statements
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P316 Get emergency medical help immediately.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P301+P316 Get emergency medical help immediately.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P317 Get emergency medical help.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.

Trade & Regulatory

HS Code 29183000
UN Number 2810
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible, acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 1

Documentation

Other Names

Allyl acetylacetate|Acetoacetic acid, allyl ester|Butanoic acid, 3-oxo-, 2-propenyl ester|AI3-04977|8HX066J62P|Butanoic acid, 3-oxo-, 2-propen-1-yl ester

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