Triethyl phosphite

CAS Number
122-52-1
EC Number
204-552-5
Abbreviation
TEP

What is Triethyl phosphite?

Triethyl phosphite (CAS 122-52-1), abbreviated TEP, is a trialkyl phosphite ester used as a reactive intermediate and stabilizer in polymer, lubricant and agrochemical manufacturing. Also known as ethyl phosphite.

Where is Triethyl phosphite used?

  • Polymer production: stabilizer and processing aid protecting polyolefins and engineering resins from oxidative degradation during high-temperature compounding
  • Lubricant and metalworking fluids: antiwear additive precursor forming protective phosphorus-containing films on metal surfaces
  • Agrochemical synthesis: building block for organophosphate active ingredients such as pesticides and herbicides via Michaelis–Arbuzov reactions
  • Catalyst systems: ligand precursor in transition metal catalysts for polymerization and fine chemical processes
  • Depending on the application it acts as a ligand, antioxidant precursor or catalyst component.

Good to know: High-purity grades are used where trace impurities affect reaction selectivity. Proper handling is required to maintain the integrity of the chemical during storage.

Commercial specifications

  • Technical grade, purity typically 97% to 99%+
  • High-purity grades for catalyst and synthesis applications
  • Clear, colorless liquid in standard drums and IBCs

Other Names (Synonyms)

Phosphorous acid, triethyl ester|Ethyl phosphite, (EtO)3P|Fosforyn trojetylowy|6B2R04S55G|TRIS(ETHOXY)PHOSPHINE|Ethyl phosphite, Et3PO3|TEP

Contact us for supply of Triethyl phosphite

Request Quote

What are the physical properties of Triethyl phosphite?

Melting Point -112 °C
Boiling Point 157.9 °C
Density 0.9629 g/cm³ @ Temp: 20 °C
Flash Point 130 °F
Appearance Colorless liquid. Insoluble in water; soluble in alcohol and ether. Combustible.
Color colorless
Odor characteristic, obnoxious, phosphiteodor
Form liquid
Water Solubility slightly soluble
Vapor Pressure <6 hPa (20 °C)
Refractive Index n 20/D 1.413(lit.)

How is Triethyl phosphite classified and handled safely? Learn More

Warning
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Triethyl phosphite?

HS Code 29209012
UN Number 2323
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 1
Call Request Quote