Triethyl phosphite
Description
Triethyl phosphite (CAS 122-52-1), commonly abbreviated as TEP, is a trialkyl phosphite ester used as a reactive intermediate and stabilizer across polymer, lubricant, and agrochemical manufacturing.
Ethyl phosphite is a recognized alternative name in trade and procurement contexts. Its value lies in its ability to act as a ligand, antioxidant precursor, or catalyst component depending on the application.
In polymer production, TEP functions as a stabilizer and processing aid, protecting polyolefins and engineering resins from oxidative degradation during high-temperature compounding processes.
Lubricant and metalworking fluid formulators incorporate it as an antiwear additive precursor, where it reacts in situ to form protective phosphorus-containing films on metal surfaces.
In agrochemical synthesis, TEP serves as a key building block for organophosphate active ingredients, including pesticides and herbicides produced via Michaelis–Arbuzov reactions.
It also acts as a ligand precursor in transition metal catalyst systems used in polymerization and fine chemical processes. This versatility makes it essential for modern chemical synthesis.
Triethyl phosphite is supplied as a clear, colorless liquid in standard drum and IBC packaging. Technical grade is the primary commercial specification, with purity levels typically ranging from 97% to 99%+.
High-purity grades are available for catalyst and synthesis applications where trace impurities affect reaction selectivity. Proper handling is required to maintain the integrity of the chemical during storage.
Physical Properties
| Melting Point | -112 °C |
| Boiling Point | 157.9 °C |
| Density | 0.9629 g/cm³ @ Temp: 20 °C |
| Flash Point | 130 °F |
| Appearance | Colorless liquid. Insoluble in water; soluble in alcohol and ether. Combustible. |
| Color | colorless |
| Odor | characteristic, obnoxious, phosphiteodor |
| Form | liquid |
| Water Solubility | slightly soluble |
| Vapor Pressure | <6 hPa (20 °C) |
| Refractive Index | n 20/D 1.413(lit.) |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29209012 |
| UN Number | 2323 |
| ADR Class | 3 |
| Packing Group | III |
| Storage Class | 3 - Flammable liquids |
| WGK (Germany) | 1 |
Documentation
Other Names
Phosphorous acid, triethyl ester|Ethyl phosphite, (EtO)3P|Fosforyn trojetylowy|6B2R04S55G|TRIS(ETHOXY)PHOSPHINE|Ethyl phosphite, Et3PO3|TEP
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