Triethyl phosphite

CAS Number
122-52-1
EC Number
204-552-5
Chemical Formula
C6H15O3P
Molecular Weight
166.16 g/mol
Abbreviation
TEP

Description

Triethyl phosphite (CAS 122-52-1), commonly abbreviated as TEP, is a trialkyl phosphite ester used as a reactive intermediate and stabilizer across polymer, lubricant, and agrochemical manufacturing. Ethyl phosphite is a recognized alternative name in trade and procurement contexts. Its value lies in its ability to act as a ligand, antioxidant precursor, or catalyst component depending on the application.

In polymer production, TEP functions as a stabilizer and processing aid, protecting polyolefins and engineering resins from oxidative degradation during high-temperature compounding processes. Lubricant and metalworking fluid formulators incorporate it as an antiwear additive precursor, where it reacts in situ to form protective phosphorus-containing films on metal surfaces.

In agrochemical synthesis, TEP serves as a key building block for organophosphate active ingredients, including pesticides and herbicides produced via Michaelis–Arbuzov reactions. It also acts as a ligand precursor in transition metal catalyst systems used in polymerization and fine chemical processes. This versatility makes it essential for modern chemical synthesis.

Triethyl phosphite is supplied as a clear, colorless liquid in standard drum and IBC packaging. Technical grade is the primary commercial specification, with purity levels typically ranging from 97% to 99%+. High-purity grades are available for catalyst and synthesis applications where trace impurities affect reaction selectivity. Proper handling is required to maintain the integrity of the chemical during storage.

Other Names (Synonyms)

Phosphorous acid, triethyl ester|Ethyl phosphite, (EtO)3P|Fosforyn trojetylowy|6B2R04S55G|TRIS(ETHOXY)PHOSPHINE|Ethyl phosphite, Et3PO3|TEP

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -112 °C
Boiling Point 157.9 °C
Density 0.9629 g/cm³ @ Temp: 20 °C
Flash Point 130 °F
Appearance Colorless liquid. Insoluble in water; soluble in alcohol and ether. Combustible.
Color colorless
Odor characteristic, obnoxious, phosphiteodor
Form liquid
Water Solubility slightly soluble
Vapor Pressure <6 hPa (20 °C)
Refractive Index n 20/D 1.413(lit.)

Documentation

Safety & Handling Learn More

Warning
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Trade & Regulatory

HS Code 29209012
UN Number 2323
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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