Triphenyl phosphite

CAS Number
101-02-0
EC Number
202-908-4
Abbreviation
TPP

What is Triphenyl phosphite?

Triphenyl phosphite (CAS 101-02-0), also sold under the trade name Advance TPP, is an organophosphorus ester used as a stabilizer and processing aid in polymer, rubber, and lubricant manufacturing.

Where is Triphenyl phosphite used?

  • Plastics compounding: incorporated into PVC and polyolefins
  • Engineering resins: suppresses discoloration and extends service life during high-temperature processing
  • Rubber and tires: processing stabilizer and mild plasticizer
  • Lubricants: antioxidant component in industrial oils and metalworking fluids
  • It also acts as an intermediate in the synthesis of other phosphorus-based flame retardants and specialty additives.

Good to know: Functions primarily as a secondary antioxidant and co-stabilizer, intercepting hydroperoxides during thermal processing to protect finished materials from degradation. In rubber it improves flow and reduces premature vulcanization side reactions.

Commercial specifications

  • Technical and industrial purity levels, typically 99%+ purity with defined acid value
  • Color limits strictly monitored for batch consistency
  • Packaging in drums and IBC containers for bulk industrial procurement

Other Names (Synonyms)

Phosphorous acid, triphenyl ester|Advance TPP|Phenyl phosphite|Tris(phenoxy)phosphine|Sumilizer TPP-R|Phenyl phosphite ((C6H5O)3P)|Phosclere T 36|TPP

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What are the physical properties of Triphenyl phosphite?

Melting Point 25 °C
Boiling Point 360 °C
Density 1.1842 g/cm³ @ Temp: 20 °C
Flash Point 425 °F
Appearance Water-white to pale-yellow solid or oily liquid; pleasant odor. Combustible.
Color Clear colorless to pale yellow
Form Liquid
Water Solubility insoluble
Vapor Pressure 5 mm Hg ( 205 °C)
Refractive Index n 20/D 1.59(lit.)
pH 1 (200g/l, H2O, 20℃)

How is Triphenyl phosphite classified and handled safely? Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Triphenyl phosphite?

HS Code 29209085
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 10 - Combustible liquids
WGK (Germany) 2
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