Triphenyl phosphite

CAS Number
101-02-0
EC Number
202-908-4
Chemical Formula
C18H15O3P
Molecular Weight
310.3 g/mol
Abbreviation
TPP

Description

Triphenyl phosphite (CAS 101-02-0), also sold under the trade name Advance TPP, is an organophosphorus ester used as a stabilizer and processing aid across polymer, rubber, and lubricant manufacturing. TPP functions primarily as a secondary antioxidant and co-stabilizer, intercepting hydroperoxides during thermal processing to protect finished materials from degradation. In plastics compounding, it is incorporated into PVC and polyolefins.

The additive is used in engineering resins to suppress discoloration and extend service life during high-temperature processing. Rubber and tire manufacturers use it as a processing stabilizer and mild plasticizer. This chemical improves flow and reduces premature vulcanization side reactions in various rubber applications. Lubricant formulators add TPP as an antioxidant component in industrial oils and metalworking fluids.

Oxidative stability under load is a key formulation requirement where this product excels. It also acts as an intermediate in the synthesis of other phosphorus-based flame retardants and specialty additives. The material is supplied as a clear to pale yellow liquid at ambient conditions. Standard commercial grades include technical and industrial purity levels, typically specified at 99%+ purity with defined acid value.

Color limits are strictly monitored to ensure consistency across different production batches. Packaging is available in drums and IBC containers suited to bulk industrial procurement for global distribution.

Other Names (Synonyms)

Phosphorous acid, triphenyl ester|Advance TPP|Phenyl phosphite|Tris(phenoxy)phosphine|Sumilizer TPP-R|Phenyl phosphite ((C6H5O)3P)|Phosclere T 36|TPP

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 25 °C
Boiling Point 360 °C
Density 1.1842 g/cm³ @ Temp: 20 °C
Flash Point 425 °F
Appearance Water-white to pale-yellow solid or oily liquid; pleasant odor. Combustible.
Color Clear colorless to pale yellow
Form Liquid
Water Solubility insoluble
Vapor Pressure 5 mm Hg ( 205 °C)
Refractive Index n 20/D 1.59(lit.)
pH 1 (200g/l, H2O, 20℃)

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Trade & Regulatory

HS Code 29209085
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 10 - Combustible liquids
WGK (Germany) 2
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