Stannic chloride

CAS Number
7646-78-8
EC Number
231-588-9
Abbreviation
SnCl4

What is Stannic chloride?

Stannic chloride (CAS 7646-78-8), also known as tin tetrachloride or SnCl4, is an inorganic tin compound supplied primarily as a fuming liquid or in hydrated form.

Where is Stannic chloride used?

  • Chemical synthesis and polymer production: Lewis acid catalyst and tin source
  • Plastics and polymer manufacturing: catalyst and stabilizer precursor in PVC and other tin-stabilized formulations
  • Pharmaceutical synthesis: Lewis acid catalyst for Friedel-Crafts reactions and other electrophilic processes
  • Indium tin oxide (ITO) coatings and conductive thin films: tin precursor deposited onto glass or plastic substrates for electronics
  • Specialty chemical manufacturing: intermediate for producing organotin compounds
  • Organotin compounds are frequently used as biocides and stabilizers in industrial formulations and coatings.

Good to know: The hydrated form is preferred where moisture sensitivity is less critical.

Commercial specifications

  • Bulk quantities packaged in drums or IBCs
  • Smaller quantities available for laboratory and pharmaceutical applications

Other Names (Synonyms)

tin tetrachloride|Tin perchloride|Stannic tetrachloride|Stannane, tetrachloro-|Tin(IV) tetrachloride|SnCl4|Tin chloride (SnCl4)|Libavius Fuming spirit

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What are the physical properties of Stannic chloride?

Melting Point -33 °C
Boiling Point 114.15 °C
Density 2.34 g/cm³
Flash Point 34 °F
Appearance Colorless, fuming, caustic liquid, that water converts into a crystalline solid, SnCl4?5H2O.Keep well stoppered. Soluble in cold water, alcohol, carbon disulfide; decomposed by hot water.
Color Colorless
Form Solution
Water Solubility reacts
Vapor Pressure 10 mm Hg ( 10 °C)
Refractive Index 1.512
pH 0.2 (60g/l, H2O, 20℃)Hydrolysis
Log P -1.67 at 20℃

How is Stannic chloride classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H290 H290
H314 H314
H318 H318
H330 H330

Precautionary Statements

P234 P234
P260 P260
P261 P261
P264 P264

Which trade and regulatory codes apply to Stannic chloride?

HS Code 28273990
UN Number 3264
ADR Class 8
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 2
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