Stannic chloride

CAS Number
7646-78-8
EC Number
231-588-9
Chemical Formula
Cl4Sn
Molecular Weight
260.5 g/mol
Abbreviation
SnCl4

Description

Stannic chloride (CAS 7646-78-8), also known as tin tetrachloride or SnCl4, is an inorganic tin compound supplied primarily as a fuming liquid or in hydrated form. It functions as a Lewis acid catalyst and tin source across chemical synthesis and polymer production. In plastics and polymer manufacturing, it acts as a catalyst and stabilizer precursor in the production of PVC and other tin-stabilized formulations. This helps control degradation during processing and ensures the durability of the final material.

Pharmaceutical synthesis relies on it as a Lewis acid catalyst for Friedel-Crafts reactions and other electrophilic processes. Controlled reactivity is critical to yield and purity in these complex chemical transformations. It is also used in the production of indium tin oxide (ITO) coatings and conductive thin films. In these applications, it serves as a tin precursor deposited onto glass or plastic substrates for electronics.

In specialty chemical manufacturing, it functions as an intermediate for producing organotin compounds. These compounds are frequently used as biocides and stabilizers in various industrial formulations and coatings. Stannic chloride is available as an anhydrous liquid and as the pentahydrate solid, with the hydrated form preferred where moisture sensitivity is less critical. Standard supply grades include technical and reagent-grade specifications.

Bulk quantities are typically packaged in drums or IBCs to ensure safe transport and storage. Smaller quantities are also available for specialized laboratory and pharmaceutical applications requiring precise measurements.

Other Names (Synonyms)

tin tetrachloride|Tin perchloride|Stannic tetrachloride|Stannane, tetrachloro-|Tin(IV) tetrachloride|SnCl4|Tin chloride (SnCl4)|Libavius Fuming spirit

Key Technical Features

  • High Purity Grade standard
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Physical Properties

Melting Point -33 °C
Boiling Point 114.15 °C
Density 2.34 g/cm³
Flash Point 34 °F
Appearance Colorless, fuming, caustic liquid, that water converts into a crystalline solid, SnCl4?5H2O.Keep well stoppered. Soluble in cold water, alcohol, carbon disulfide; decomposed by hot water.
Color Colorless
Form Solution
Water Solubility reacts
Vapor Pressure 10 mm Hg ( 10 °C)
Refractive Index 1.512
pH 0.2 (60g/l, H2O, 20℃)Hydrolysis
Log P -1.67 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H290 H290
H314 H314
H318 H318
H330 H330

Precautionary Statements

P234 P234
P260 P260
P261 P261
P264 P264

Trade & Regulatory

HS Code 28273990
UN Number 3264
ADR Class 8
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 2
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