SoleChem

Titanium tetrachloride

CAS
7550-45-0
EC
231-441-9
Mol. Weight
189.7 g/mol

Description

Titanium tetrachloride (CAS 7550-45-0), commonly referenced as TiCl4, is a high-purity inorganic compound used primarily as a catalyst precursor and chemical intermediate across several industrial sectors.

Its reactivity with moisture and oxygen makes it a critical building block for producing titanium-based compounds at scale. In polyolefin manufacturing, TiCl4 is a core component in Ziegler-Natta catalyst systems.

These systems are used to produce polypropylene and polyethylene, directly influencing polymer stereoregularity and molecular weight distribution. Textile and paper processors use it as a surface treatment agent.

This application improves mordanting, fiber adhesion, and coating receptivity. In pharmaceutical synthesis, it functions as a Lewis acid catalyst enabling stereoselective reactions and chiral intermediate production.

Personal care and cosmetics manufacturers use TiCl4 as a precursor to synthetic titanium dioxide pigments. These pigments are applied in sunscreens, foundations, and various opacifying formulations.

Titanium tetrachloride is supplied as a fuming liquid, typically in stabilized, moisture-protected packaging such as sealed drums or ISO containers. It is available in technical and high-purity catalyst grades.

Specifications are tailored to polymerization catalyst production or chemical synthesis requirements. Buyers should confirm purity thresholds and metal impurity limits based on end-use sensitivity.

This is particularly important for pharmaceutical or catalyst applications where strict quality control is required. Proper handling protocols must be maintained to ensure the stability of the chemical compound.

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Physical Properties

Melting Point -24.1 °C
Boiling Point 136.4 °C
Density 1.726 g/cm³
Flash Point 46 °F
Appearance Colorless liquid. Fumes strongly when exposed to moist air, forming a dense and persistent white cloud. Soluble in dilute hydrochloric acid; soluble in water with evolution of heat; concentrated aqueous solutions are stable and corrosive; dilute solutions
Color Light yellow to dark brown
Form Solution
Water Solubility reacts
Vapor Pressure 50 mm Hg ( 55 °C)
Refractive Index 1.61

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08
Hazard Statements
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H330 Fatal if inhaled
H335 May cause respiratory irritation
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
Precautionary Statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P319 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P333+P317 Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 28273990
UN Number 3289
ADR Class 6.1
Packing Group II
Storage Class 6.1B - Non-combustible, acute toxic Cat. 1 and 2 very toxic hazardous materials
WGK (Germany) 2

Documentation

Other Names

TiCl4|Titanic chloride|Titanium chloride (TiCl4)|Tetrachlorure de titane|Titanium chloride (TiCl4) (T-4)-|Titanium chloride

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