Titanium isopropoxide

CAS Number
546-68-9
EC Number
208-909-6
Chemical Formula
C3H8O.1/4Ti
Molecular Weight
284.22 g/mol
Abbreviation
TTIP

Description

Titanium isopropoxide (CAS 546-68-9), commonly abbreviated as TTIP and also known as tetraisopropyl orthotitanate, is a reactive organotitanium compound used as a catalyst precursor. It functions as a sol-gel processing agent across specialty chemical manufacturing. It enables controlled deposition of titanium dioxide coatings and serves as a crosslinking agent in polymer systems.

In sol-gel and thin-film processes, TTIP is hydrolyzed to deposit TiO₂ layers on glass, metal, and plastic substrates for photocatalytic, anti-reflective, or barrier coating applications. Polymer manufacturers use it as a crosslinker for polyesters and alkyd resins, improving adhesion and film integrity in coatings and adhesives for industrial use.

In personal care and cosmetic formulations, it functions as a surface-modification agent for treating pigment particles, particularly titanium dioxide used in sunscreens and color cosmetics. Pharmaceutical and biotech applications include its use as a catalyst in stereoselective synthesis, notably in asymmetric epoxidation reactions for high-purity chemical production.

TTIP is supplied as a moisture-sensitive liquid, typically at 97% or higher purity. Technical and reagent grades are the most commonly available for industrial procurement. Packaging ranges from small laboratory quantities to bulk drums under inert atmosphere. Handling and storage requirements under dry, inert conditions are standard for this material.

Other Names (Synonyms)

titanium(IV) isopropoxide|tetraisopropyl orthotitanate|titanium tetraisopropoxide|Titanium isopropylate|Titanium tetraisopropylate|TETRAISOPROPYL TITANATE|Tilcom TIPT|Isopropyl orthotitanate|TTIP

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point ~20 °C (approx)
Boiling Point 220 °C @ Press: 760 Torr
Density 0.9711 g/cm³ @ Temp: 20 °C
Flash Point 72 °F
Appearance colourless to light yellow liquid
Color Colorless to pale yellow
Form Liquid
Water Solubility HYDROLYSIS
Vapor Pressure 60.2hPa at 25℃
Refractive Index n 20/D 1.464(lit.)
Log P 0.05

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS07· Irritant

Hazard Statements

H226 Flammable liquid and vapor
H318 Causes serious eye damage
H319 Causes serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Trade & Regulatory

HS Code 29051900
UN Number 2413
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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