Mercury chloride

CAS Number
10112-91-1
EC Number
233-307-5

What is Mercury chloride?

Mercury(I) chloride (CAS 10112-91-1), commercially known as calomel, is an inorganic mercury salt used as a reference electrode material and catalyst in specialized industrial and laboratory settings.

Where is Mercury chloride used?

  • Analytical chemistry and precision measurement: benchmark compound
  • Saturated calomel electrodes (SCE): active material
  • Electrochemical analysis, pH measurement and corrosion testing: standard reference electrodes
  • Electronics manufacturing: supports calibration processes requiring stable, reproducible electrode potentials
  • Pharmaceutical and chemical research: catalyst
  • In select organic synthesis reactions it offers specific selectivity advantages.
  • Regulatory and analytical standards work

Commercial specifications

  • Small quantities consistent with specialized, low-volume demand profile

Other Names (Synonyms)

Calomel|Mercury chloride (Hg2Cl2)|Chloromercury|Mercurous chloride|Mercury(I) chloride

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What are the physical properties of Mercury chloride?

Melting Point 400 °C (sublm)
Boiling Point 384 °C
Density 7.15 g/cm³
Appearance White, rhombic crystals or crystalline powder; odorless. Stable in air but darkens on exposure to light.decomposed by alkalies. Insoluble in water, ether, alcohol, and cold dilute acids.
Color White
Odor Odorless
Form powder
Water Solubility Soluble in (0.002g/L )water.
Vapor Pressure 1.7 mm Hg at 236 °C

How is Mercury chloride classified and handled safely? Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Mercury chloride?

UN Number 2811
ADR Class 6.1
Packing Group III
WGK (Germany) 3
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