Mercury chloride

CAS Number
10112-91-1
EC Number
233-307-5
Chemical Formula
Cl2Hg2
Molecular Weight
472.09 g/mol

Description

Mercury(I) chloride (CAS 10112-91-1), commercially known as calomel, is an inorganic mercury salt used as a reference electrode material and catalyst in specialized industrial and laboratory settings. Its electrochemical stability makes it a benchmark compound in analytical chemistry and precision measurement applications. Calomel is the active material in saturated calomel electrodes (SCE).

These serve as standard reference electrodes in electrochemical analysis, pH measurement, and corrosion testing across laboratory and industrial quality control environments. In electronics manufacturing, it supports calibration processes where stable, reproducible electrode potentials are required. Pharmaceutical and chemical research facilities use it as a catalyst.

It is utilized in select organic synthesis reactions where mercury-based catalysis offers specific selectivity advantages. Historically significant in pharmaceutical compounding, it remains a reference compound. It is used in regulatory and analytical standards work. Mercury(I) chloride is supplied as a white to off-white crystalline powder available in reagent-grade and analytical-grade specifications.

These grades meet laboratory and industrial purity requirements. Packaging is typically offered in small quantities consistent with its specialized, low-volume demand profile.

Other Names (Synonyms)

Calomel|Mercury chloride (Hg2Cl2)|Chloromercury|Mercurous chloride|Mercury(I) chloride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 400 °C (sublm)
Boiling Point 384 °C
Density 7.15 g/cm³
Appearance White, rhombic crystals or crystalline powder; odorless. Stable in air but darkens on exposure to light.decomposed by alkalies. Insoluble in water, ether, alcohol, and cold dilute acids.
Color White
Odor Odorless
Form powder
Water Solubility Soluble in (0.002g/L )water.
Vapor Pressure 1.7 mm Hg at 236 °C

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

UN Number 2811
ADR Class 6.1
Packing Group III
WGK (Germany) 3
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