Ammonium bicarbonate

CAS Number
1066-33-7
EC Number
213-911-5
Chemical Formula
CH2O3.H3N
Molecular Weight
79.056 g/mol

Description

Ammonium bicarbonate (CAS 1066-33-7), also known as E503(ii) and ammonium acid carbonate, is an inorganic salt that decomposes cleanly into ammonia, carbon dioxide, and water upon heating. This decomposition behavior makes it a practical leavening and pH-adjusting agent across food, pharmaceutical, and industrial applications. In baked goods, particularly flat or low-moisture products like crackers, cookies, and hard biscuits, it acts as a chemical leavening agent.

The compound produces gas without leaving residual salts that affect taste. Pharmaceutical manufacturers use it as a pH buffer and excipient in tablet formulations where controlled alkalinity is required during processing. In agriculture, it functions as a nitrogen source in fertilizer blends and as a feed additive where buffering of digestive pH is targeted. Personal care formulators apply it as a pH regulator in creams and cleansing products.

These applications require mild alkaline adjustment to maintain product stability. Ammonium bicarbonate is supplied as a white crystalline powder or granules. Standard commercial grades include food-grade (FCC) and pharmaceutical-grade material. The product is also available in USP, BP, and technical-grade material for industrial use. Packaging typically ranges from small bags to bulk quantities, with food and pharma grades subject to purity and heavy metal specifications.

Other Names (Synonyms)

NH4HCO3|ammonium acid carbonate|Ammonium hydrogencarbonate|Monoammonium carbonate|Carbonic acid, monoammonium salt|Acid ammonium carbonate|Ammonium hydrogencarbonat|Ammonium bicarbonate (1:1)|E503(ii)

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point 107 °C (decomp)
Boiling Point 143.04°C (rough estimate)
Density 1.586 g/cm³
Appearance Ammonium bicarbonate is a white crystalline solid with a faint ammonia odor.
Color White
Odor faint ammonia odor
Form Solid
Water Solubility 220 g/L (20 ºC)
Vapor Pressure 67 hPa (20 °C)
Refractive Index 1.4164 (estimate)
pH 7.0-8.5 (25℃, 1M in H2O)
Log P -0.809 (est)

Safety & Handling (Learn More)

Warning
GHS07· Irritant

Hazard Statements

H302 Harmful if swallowed
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P330 Rinse mouth.
P501 Dispose of contents/container in accordance with local regulations.
P301+P317 Get emergency medical help.

Trade & Regulatory

HS Code 28369990
UN Number 3077
Storage Class 13 - Non Combustible Solids
WGK (Germany) 1

Documentation

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