Ammonium bicarbonate
Description
Ammonium bicarbonate (CAS 1066-33-7), also known as E503(ii) and ammonium acid carbonate, is an inorganic salt that decomposes cleanly into ammonia, carbon dioxide, and water upon heating.
This decomposition behavior makes it a practical leavening and pH-adjusting agent across food, pharmaceutical, and industrial applications. In baked goods, particularly flat or low-moisture products like crackers, cookies, and hard biscuits, it acts as a chemical leavening agent.
The compound produces gas without leaving residual salts that affect taste. Pharmaceutical manufacturers use it as a pH buffer and excipient in tablet formulations where controlled alkalinity is required during processing.
In agriculture, it functions as a nitrogen source in fertilizer blends and as a feed additive where buffering of digestive pH is targeted. Personal care formulators apply it as a pH regulator in creams and cleansing products.
These applications require mild alkaline adjustment to maintain product stability. Ammonium bicarbonate is supplied as a white crystalline powder or granules. Standard commercial grades include food-grade (FCC) and pharmaceutical-grade material.
The product is also available in USP, BP, and technical-grade material for industrial use. Packaging typically ranges from small bags to bulk quantities, with food and pharma grades subject to purity and heavy metal specifications.
Physical Properties
| Melting Point | 107 °C (decomp) |
| Boiling Point | 143.04°C (rough estimate) |
| Density | 1.586 g/cm³ |
| Appearance | Ammonium bicarbonate is a white crystalline solid with a faint ammonia odor. |
| Color | White |
| Odor | faint ammonia odor |
| Form | Solid |
| Water Solubility | 220 g/L (20 ºC) |
| Vapor Pressure | 67 hPa (20 °C) |
| Refractive Index | 1.4164 (estimate) |
| pH | 7.0-8.5 (25℃, 1M in H2O) |
| Log P | -0.809 (est) |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 28369990 |
| UN Number | 3077 |
| Storage Class | 13 - Non Combustible Solids |
| WGK (Germany) | 1 |
Documentation
Other Names
NH4HCO3|ammonium acid carbonate|Ammonium hydrogencarbonate|Monoammonium carbonate|Carbonic acid, monoammonium salt|Acid ammonium carbonate|Ammonium hydrogencarbonat|Ammonium bicarbonate (1:1)|E503(ii)
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