SoleChem

o-Tolidine

CAS
119-93-7
EC
204-358-0
Mol. Weight
212.29 g/mol

Description

o-Tolidine (CAS 119-93-7), also known commercially as 3,3'-dimethylbenzidine or DMB, is an aromatic diamine used as a chemical intermediate in the production of dyes, pigments, and curing agents.

Its bifunctional amine structure makes it a reactive building block for synthesizing azo colorants and polyurea-based systems across several industrial sectors. In the dye and pigment industry, it is a key intermediate.

This chemical is essential for manufacturing diazo-based yellow and orange pigments used in printing inks and packaging colorants. Textile and leather processors use DMB-derived dyes to achieve high-fastness coloration.

These dyes are effective on both natural and synthetic substrates. In polymer and elastomer manufacturing, it functions as a curing agent for polyurethane and polyurea systems where controlled crosslink density is required.

Specialty coatings formulators also source it as a precursor for producing performance pigments with strong lightfastness characteristics. This ensures long-lasting color stability in various industrial coating applications.

The product is supplied as a solid, typically in flake or crystalline powder form. Technical grade is the standard commercial specification for industrial intermediate applications and large-scale manufacturing.

It is available in bulk quantities suited to pigment manufacturers and polymer processors. Packaging options range from drums to bulk bags depending on specific volume requirements and logistical needs of the client.

Contact us for supply of o-Tolidine

Request Quote

Physical Properties

Melting Point 129-131 °C
Boiling Point 300 °C
Density 1.234 g/cm³
Flash Point 244 °C
Appearance o-Tolidine is a white to reddish crystal or powder. Darkens on exposure to air. Often used in paste or wet cake form. Used as a basis for many dyes.
Color light brown
Form powder (may contain lumps)
Water Solubility Slightly soluble in water.
Refractive Index n 20/D 1.341

Safety & Handling (Learn More)

Danger GHS07 GHS08 GHS09
Hazard Statements
H302 Harmful if swallowed
H341 Suspected of causing genetic defects
H350 May cause cancer
H351 Suspected of causing cancer
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P301+P317 Get emergency medical help.

Trade & Regulatory

HS Code 29215900
UN Number 3082
ADR Class 9
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3

Documentation

Other Names

3,3'-dimethylbenzidine|4-(4-amino-3-methylphenyl)-2-methylaniline|DMB

Related Products

Need a chemical? Get a quote within 24 hours.

Call Request Quote