Sodium hydroxide

CAS Number
1310-73-2
EC Number
215-185-5
E Number
E524
Abbreviation
NaOH

What is Sodium hydroxide?

Sodium hydroxide (CAS 1310-73-2), also sold as caustic soda or lye, is a strong inorganic base used to control pH and neutralize acids in industrial and food-grade processing.

Where is Sodium hydroxide used?

  • Water treatment: raises pH, precipitates heavy metals, conditions water for safe distribution
  • Pulp and paper: breaks down lignin during the kraft process, enabling cellulose separation at scale
  • Textile and leather: drives mercerization of cotton and assists in dehairing hides
  • Food processing: curing olives, pretzel glazing, pH adjustment in cocoa processing
  • As E524, it is approved for direct food contact applications.
  • Refining of vegetable oils.
  • Aluminum production: dissolving and purifying bauxite ore.
  • Metal surface treatment: pH adjustment, alkalization, degreasing, and pickling.
  • Production of soaps and detergents.

Good to know: Standard grades include food-grade (FCC), pharmaceutical (USP/BP/Ph. Eur.), and technical grade. Membrane cell grades with low chloride content are available for applications requiring high purity.

Formulation notes

  • Corrosive to most metals.

Typical specification

  • Supplied in solid (flake or pearl) and liquid (30–50% concentration) forms depending on the application.
  • 32% solution has a mass fraction of 31–33%.
  • Microprill grades are solid, molten caustic soda beads with a consistent diameter of less than 1 mm, ensuring fast and easy dissolution in common solvents like water, ethanol, and methanol.
  • NaOH titre is between 97.0% and 100.5%.

Regulatory status

  • Harmonized classification and labeling are mandatory according to Annex VI of the CLP regulation (EC No 1272/2008).

Storage, packaging and handling

  • Dissolution in water or neutralization with acid liberates substantial heat that may ignite combustible materials.
  • Strongly corrosive; corrosion-resistant tanks and pipes must be used, solid product must be protected from moisture, and dilution must be controlled.

Frequently asked questions about Sodium hydroxide

What are the typical uses of sodium hydroxide in metal surface treatment?
It is used for surface cleaning, oxide removal, and pre-coating preparation.
How does sodium hydroxide function in soap and detergent production?
It saponifies triglycerides to form sodium salts of fatty acids and glycerol.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

white caustic|sodium hydrate|soda lye|caustic soda|lye|Soda, caustic|Rohrputz|Sodium hydroxide (Na(OH))|NaOH|E524

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What are the physical properties of Sodium hydroxide?

Melting Point 323 °C
Boiling Point 1388 °C
Density 2.13 g/cm³ @ Temp: 25 °C
Flash Point 176-178°C
Appearance NaOH is a white, odorless, deliquescent material sold as pellets, flakes, lumps, or sticks. Aqueous solutions are known as soda lye
Color White
Odor Odorless
Form beads
Water Solubility SOLUBLE
Vapor Pressure 1 mm Hg ( 745 °C)
Refractive Index 1,473-1,475
pH >14 (100g/l, H2O, 20℃)

How is Sodium hydroxide classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H318 Causes serious eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Sodium hydroxide?

HS Code 2815 11 00
UN Number 1824
ADR Class 8
Packing Group II
Storage Class 8B - Non-combustible corrosive hazardous materials
WGK (Germany) 1
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