SoleChem

Lithium hydroxide

CAS
1310-65-2
EC
215-183-4
Mol. Weight
24.0 g/mol

Description

Lithium hydroxide (CAS 1310-65-2), also known as lithium hydrate, is a strong inorganic base supplied in both anhydrous and monohydrate forms. It is used across battery manufacturing, lubricant production, and chemical synthesis as an alkalizing agent and catalyst precursor.

Demand has grown sharply with the expansion of lithium-ion battery supply chains, where it serves as a direct cathode precursor material. In electric vehicle and energy storage battery production, it is the preferred feedstock for manufacturing high-nickel NMC and NCA cathode active materials.

Lubricant manufacturers use it to saponify fatty acids, producing lithium-based greases valued for high-temperature and multi-purpose performance. In pharmaceuticals and specialty chemicals, it functions as a pH regulator and base catalyst in synthesis processes requiring precise alkalinity control.

Paper and textile processors apply it for mercerization and fiber treatment, where controlled alkaline conditions affect surface structure and dye uptake. Lithium hydroxide is available as a white powder or granules in both anhydrous and monohydrate forms.

Battery-grade lithium hydroxide monohydrate is the dominant commercial specification, with purity typically at 56.5% LiOH minimum. It features low impurity thresholds for metals such as sodium, calcium, and sulfate to ensure high performance in electrochemical applications.

Technical and reagent grades are also available for industrial and laboratory procurement. These grades meet various industrial requirements and are often tested against rigorous quality standards such as ACS or USP depending on the specific application needs.

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Physical Properties

Melting Point 450 °C
Boiling Point 925°C
Density 1.46 g/cm³
Appearance White solid
Color White to light yellow
Odor odorless
Form Solid
Water Solubility 113 g/L (20 ºC)
pH 12 (50g/l, H2O, 50℃)

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08
Hazard Statements
H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H331 Toxic if inhaled
H360 May damage fertility or the unborn child
H370 Causes damage to organs
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 28252010
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 1

Documentation

Other Names

lithium hydrate|LiOH|lithium hydroxide anhydrous|Lithium hydroxide (Li(OH))|903YL31JAS|RefChem:5957|Bluesil SLT-CATA 51015

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