Lithium hydroxide monohydrate

CAS Number
1310-66-3
EC Number
603-454-3
Chemical Formula
H2O.HLiO
Molecular Weight
42.0 g/mol

Description

Lithium hydroxide monohydrate (CAS 1310-66-3) is a high-purity inorganic base used across battery manufacturing, industrial chemistry, and specialty lubrication. Its controlled alkalinity and reactivity profile make it a preferred source of lithium. In processes where anhydrous forms would introduce handling or reactivity complications, this monohydrate form is preferred. In lithium-ion battery production, it serves as a precursor for cathode active materials.

Consistent purity directly impacts cell performance in materials such as LiNiMnCoO₂ (NMC) and LiNiCoAlO₂ (NCA). Lubricant manufacturers use it to saponify fatty acids, producing lithium-based greases. These greases outperform conventional soaps in high-temperature and high-load applications. In water treatment, it adjusts pH in closed-loop systems, particularly in nuclear and industrial cooling circuits.

Precise alkalinity control prevents corrosion in these sensitive environments. Pharmaceutical and specialty chemical producers also use it as a catalyst or base in synthesis steps requiring a soluble lithium source. Lithium hydroxide monohydrate is supplied as a white granular powder or fine powder. Particle size is selected based on dissolution rate requirements, with standard commercial grades including technical and battery-grade.

For pharmaceutical applications, USP-grade material is available to meet strict regulatory requirements. Battery-grade specifications are increasingly the benchmark for procurement in the modern market. These grades feature tightly controlled limits on sodium, calcium, and sulfate content. This ensures the highest level of performance and stability in advanced chemical manufacturing and energy storage applications.

Other Names (Synonyms)

lithium hydroxide hydrate|Lithium hydroxide (Li(OH)), monohydrate|Lithium hydroxide (USP)|RefChem:799552

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 450 °C
Boiling Point 920 °C
Density 1.51 g/cm³
Appearance white crystals or pellets
Color White to cream or yellow
Odor Odorless
Form Solid
Water Solubility 109 g/L (20 ºC)
pH ~12 (25℃, 1M in H2O)

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 28252000
UN Number 2680
ADR Class 8
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 2
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