Potassium hydroxide

CAS Number
1310-58-3
EC Number
215-181-3
E Number
E525
Abbreviation
KOH

What is Potassium hydroxide?

Potassium hydroxide (CAS 1310-58-3), also known as potash lye and designated E525 in food applications, is a strong inorganic alkali.

Where is Potassium hydroxide used?

  • Soap and detergent manufacturing: alkali for soft and liquid soaps
  • Food processing: acidity regulator in cocoa treatment, noodle production and confectionery
  • Fertilizers: potassium source in liquid nutrient formulations
  • Pulp and paper: fiber processing and bleaching
  • Water treatment: pH correction and pipe corrosion prevention
  • Water treatment: regulation of pH and removal of heavy metals, CO2, and other impurities.
  • It also serves as a pH regulator, saponification agent and chemical intermediate where sodium-based alternatives are unsuitable.

Formulation notes

  • Reacts with ammonium salts, releasing ammonia and creating a fire risk.
  • Never add water to potassium hydroxide; for solutions or dilutions always add it slowly to the water.

Typical specification

  • Water solubility: 110 g/100 ml at 25°C (very high).
  • Most commonly available as a 45 to 50% concentrated solution.
  • Available as a 28% w/w aqueous solution containing 72% w/w water.
  • The 28% aqueous solution is also designated 5N.

Regulatory status

  • Classified as harmonized under EU Regulation 1272/2008 (CLP).
  • Potassium hydroxide solution has UN number 1814, hazard class 8, packing group II-III.
  • Carries hazard statement H314, causing severe skin burns and serious eye damage.
  • EU CLP harmonised classification index number: 019-002-00-8.

Storage, packaging and handling

  • When moist, attacks metals such as aluminum, tin, lead, and zinc, producing flammable hydrogen.
  • Store separated from food and feed, strong acids and metals, only in its original packaging, dry, well closed, in an area without drains or sewer access.
  • Store only in the original container, dry, well closed, in an area without access to drains or sewers.

Frequently asked questions about Potassium hydroxide

How does potassium hydroxide behave when dissolved in water?
Potassium hydroxide is a strong alkali that dissociates completely in water into potassium and hydroxide ions; dissolution is strongly exothermic.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

potassium hydrate|potash lye|KOH|E525|caustic potash|lye|Potassium hydroxide (K(OH))|Hydroxyde de potassium

Contact us for supply of Potassium hydroxide

Request Quote

What are the physical properties of Potassium hydroxide?

Melting Point 380 °C
Boiling Point 1327 °C
Density 2.044 g/cm³
Flash Point 52 °F
Appearance White, deliquescent pieces, lumps, sticks, pellets, or flakes having a crystalline fracture. Keep well stoppered, absorbs water and carbon dioxide from the air. Soluble in water, alcohol, glycerol; slightly soluble in ether.
Color white
Odor Odorless
Form powder
Water Solubility soluble
Vapor Pressure 1 mm Hg ( 719 °C)
Refractive Index n 20/D 1.421
pH 14 (56g/l, H2O, 20℃)
Log P -1.380 (est)

How is Potassium hydroxide classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H301 Toxic if swallowed
H302 Harmful if swallowed
H304 May be fatal if swallowed and enters airways

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Potassium hydroxide?

HS Code 28152000
UN Number 2924
ADR Class 3
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 1
Call Request Quote