Oxalic acid

CAS Number
144-62-7
EC Number
205-634-3

What is Oxalic acid?

Oxalic acid (CAS 144-62-7) is a dicarboxylic organic acid used as a reducing agent, chelating agent, and pH regulator in industrial processing.

Where is Oxalic acid used?

  • Water treatment and industrial cleaning: dissolves iron oxide and rust deposits from boilers, heat exchangers, and pipework
  • Textile and paper: bleaching and stripping agent that removes discoloration from natural fibers and pulp
  • Mining and hydrometallurgy: precipitates rare earth elements and other metals from leach solutions
  • Personal care: pH adjuster and chelating agent in hair bleaching and skin-lightening products
  • It removes metal ions and mineral deposits from surfaces and process streams.
  • Used in leather processing.
  • Used to make pigments, inks, dye fixatives for wool, and fabric bleaches.
  • Used in water treatment to remove heavy metals and impurities.
  • Used in organic and conventional beekeeping for Varroa control.
  • Used for the precipitation of metals such as gold, silver, copper and mercury.

Formulation notes

  • Attacks certain types of plastic.
  • For rust removal on metal machinery parts, soak in a solution of ten parts water to one part oxalic acid.

Typical specification

  • ACS Grade has an assay specification of 99.5-102.5%.
  • ACS Grade has a maximum heavy metals content of 5 ppm.
  • Dihydrate form has CAS number 6153-56-6.

Regulatory status

  • Has the EU index number 607-006-00-8.
  • Has the UN number 3261.
  • Classified as harmful if swallowed (H302) under the harmonised CLP classification.
  • For transport, classified under UN Class 8 with packing group III.
  • The harmonised classification must be supplemented by the supplier through self-classification where applicable.

Storage, packaging and handling

  • Reacts with some silver compounds to produce explosive silver oxalate.
  • Should be stored separately from strong oxidants, food and feed; keep dry and well closed.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

oxalic acid anhydrous|HOOCCOOH|H2ox|ethanedionic acid|ethanedioic acid|ethane-1,2-dioic acid|(COOH)2|hydrogen oxalate

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What are the physical properties of Oxalic acid?

Melting Point 189.5 °C (decomp)
Boiling Point 158 °C
Density 1.9 g/cm³
Flash Point 101-157°C
Appearance Oxalic acid is a colorless, odorless powder, or granular solid. The anhydrous form (COOH)2 is an odorless, white solid; the solution is a colorless liquid.
Color White
Odor odorless
Form Liquid
Water Solubility 90 g/L (20 ºC)
Vapor Pressure <0.01 mm Hg ( 20 °C)
Refractive Index 1.4261 (estimate)
pH 1 (100g/l, H2O, 20℃)
Log P -1.7 at 23℃

How is Oxalic acid classified and handled safely? Learn More

Warning
GHS07· Irritant GHS05· Corrosive GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Oxalic acid?

HS Code 29171110
UN Number 3261
ADR Class 8
Packing Group III
WGK (Germany) 1
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