SoleChem

Chromic acid

Inorganic Acids Textile, Leather & Paper
CAS
7738-94-5
EC
231-801-5
Mol. Weight
118.010 g/mol

Description

Chromic acid (CAS 7738-94-5) is a strong inorganic oxidizing acid used primarily in metal surface treatment and industrial finishing operations. In practice, it exists as an aqueous solution of chromium trioxide and is sourced and handled in that form by most industrial buyers.

In metal finishing and electroplating, chromic acid is the active constituent of hard chrome and decorative chrome plating baths. It produces wear-resistant and corrosion-inhibiting coatings on various industrial components.

Anodizing operations for aluminum use chromic acid electrolyte processes where a thin, corrosion-resistant oxide layer is required. This is particularly critical in specialized aerospace and defense applications.

In the textile and leather industries, it functions as an oxidizing bleach and surface modifier. This improves dye uptake and prepares fiber substrates for various types of downstream processing.

Mining and metals operations use it in passivation treatments to protect metal surfaces against oxidation during storage and transit. This ensures the integrity of the metal before it reaches the end user.

Chromic acid is supplied as an aqueous solution, with chromium trioxide dissolved in water to produce the active acid. Technical grade is the standard commercial form for most industrial applications.

Concentration is typically specified by the buyer according to specific process requirements. Industrial supply is subject to regulatory controls in many jurisdictions due to hexavalent chromium content.

Buyers should confirm compliance documentation alongside standard quality specifications. Proper handling and storage protocols must be maintained to ensure safety and environmental protection during use.

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Physical Properties

Melting Point 196 °C
Boiling Point 250 °C (decomposes)
Density 1.67-2.82 g/cm³
Appearance Chromic acid is a dark purplish-red odorless flakes or crystalline powder
Color Clear, orange
Odor Odorless
Form Liquid
Water Solubility HIGHLY Soluble
pH 3.03(1 mM solution);2.33(10 mM solution);2.06(100 mM solution)

Safety & Handling (Learn More)

Danger GHS03 GHS05 GHS06 GHS07 GHS08 GHS09
Hazard Statements
H271 May cause fire or explosion; strong Oxidizer
H300 Fatal if swallowed
H301 Toxic if swallowed
H310 Fatal in contact with skin
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H330 Fatal if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H340 May cause genetic defects
H341 Suspected of causing genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P283 Wear fire-resistant/flame-retardant clothing.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P405 Store locked up.
P420 Store away from other materials.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P333+P317 Get emergency medical help.
P342+P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P301+P330+P331 Rinse mouth. Do NOT induce vomiting.
P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P371+P380+P375 Evacuate area.

Trade & Regulatory

UN Number 1463

Documentation

Other Names

Tetraoxochromic acid|Chromic(VI) acid|[CrO2(OH)2]|H2CrO4|Chromic acid (H2CrO4)|Acide chromique|SA8VOV0V7Q|dihydrogen(tetraaoxidochromate)

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