Crotonic acid

CAS Number
3724-65-0
EC Number
223-077-4
Chemical Formula
C4H6O2
Molecular Weight
86.09 g/mol
FEMA Number
FEMA 3908

Description

Crotonic acid (CAS 3724-65-0), also known as beta-methylacrylic acid, is an unsaturated monocarboxylic acid used primarily as a reactive monomer and chemical intermediate across polymer and specialty chemical manufacturing. Its conjugated double bond makes it a functional building block for synthesizing resins, coatings, and copolymers with targeted performance characteristics. In polymer chemistry, it is copolymerized with vinyl acetate.

This process produces hair-fixative resins used in aerosol sprays and styling formulations. Agricultural chemical manufacturers use it as an intermediate in synthesizing crop protection actives and adjuvant systems. In food and flavor applications, it functions as a flavoring agent and acidulant in approved formulations, particularly where a mild acidity profile is required for specific end products.

Pharmaceutical producers also source it as a synthetic intermediate for active pharmaceutical ingredient (API) manufacturing. It is supplied as a white to off-white crystalline solid for industrial use. Standard commercial grades include technical and pharmaceutical-grade material, with purity levels typically ranging from 99% upward for high-specification applications. Packaging is available in small drums through to bulk quantities.

Other Names (Synonyms)

beta-methylacrylic acid|beta-methacrylic acid|alpha-crotonic acid|alpha-butenoic acid|3-methylacrylic acid|2-butenic acid|CTA|(E)-but-2-enoic acid

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 72 °C
Boiling Point 185 °C
Density 1.018 g/cm³ @ Temp: 15 °C
Flash Point 190 °F
Appearance Crotonic acid is a white or colorless, crystalline solid with a pungent odor. May be transported as a molten liquid.
Odor at 0.10 % in propylene glycol. roasted burnt
Water Solubility soluble
Vapor Pressure 0.19 mm Hg ( 20 °C)
Refractive Index 1.4210 (estimate)
Log P 0.720

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic

Hazard Statements

H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.

Trade & Regulatory

UN Number 2823
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 3
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