trans-Crotonic acid

CAS Number
107-93-7
EC Number
203-533-9
Chemical Formula
C4H6O2
Molecular Weight
86.09 g/mol
FEMA Number
FEMA 3908

Description

Trans-Crotonic acid (CAS 107-93-7), also known by its FEMA 3908 designation, is an unsaturated organic acid used as a flavoring agent and acidulant in food and cosmetic applications. It functions as a pH regulator, preservative component, and reactive monomer in polymer synthesis for coating and adhesive systems. In food and beverage formulations, it contributes flavor modulation and mild acidulant activity.

The material is recognized under its FEMA code for use in approved flavoring compositions. Cosmetic and personal care formulators incorporate it into film-forming polymers and fixative resins for hair care products. In these applications, it provides controlled hold and flexibility. In industrial coating systems, it acts as a copolymerizable monomer to modify resin hardness, adhesion, and film durability for various surfaces.

Its buffering capacity also makes it relevant in preservation systems where pH control supports antimicrobial efficacy. Trans-Crotonic acid is supplied as a white to off-white crystalline solid for industrial use. Standard commercial grades include food-grade material meeting FEMA specifications and technical-grade product for polymer applications. Packaging is typically offered in kilogram quantities for specialty use and larger bulk formats.

Other Names (Synonyms)

trans-2-butenoic acid|Butenoic Acid|(E)-but-2-enoic acid|(2E)-2-butenoic acid|beta-methylacrylic acid|beta-methacrylic acid|alpha-crotonic acid|alpha-butenoic acid

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 72 °C
Boiling Point 185 °C
Density 1.027 g/mL at 25 °C(lit.)
Flash Point 190 °F
Appearance White to light yellow crystalline flakes
Color White to light yellow
Odor at 1.00 %. milky
Form Crystalline Flakes
Water Solubility 94 g/L (25 ºC)
Vapor Pressure 0.19 mm Hg ( 20 °C)
Refractive Index 1.4228
pH 3 (10g/l, H2O, 20℃)
Log P 0.85 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic

Hazard Statements

H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29161940
UN Number 2823
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 3
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