Itaconic acid

CAS Number
97-65-4
EC Number
202-586-1

What is Itaconic acid?

Itaconic acid (CAS 97-65-4) is a bio-based unsaturated dicarboxylic acid produced through fungal fermentation; a renewable alternative to petrochemical monomers in polymer synthesis.

Where is Itaconic acid used?

  • Polymer and resin manufacturing: copolymerized with acrylic acid, styrene, or vinyl acetate to modify adhesion, flexibility, and hydrophilicity in coatings, binders, and pressure-sensitive adhesives
  • Superabsorbent polymers: tunes water absorption in hygiene and agricultural products
  • Personal care: co-monomer in film-forming polymers
  • Food and flavor: acidulant and flavoring agent for beverage and confectionery systems needing precise pH control and stability
  • Its reactive double bond and dual carboxylic groups make it a building block for specialty resins, coatings, and superabsorbent materials.

Good to know: Buyers should confirm feedstock origin with suppliers for bio-based claims.

Commercial specifications

  • Purity typically 99% or above
  • Bags, supersacks, and bulk quantities

Other Names (Synonyms)

propylenedicarboxylic acid|methylenebutanedioic acid|2-propene-1,2-dicarboxylic acid|2-methylidenebutanedioic acid|2-methylenesuccinic acid|2-methylenebutanedioic acid|METHYLENESUCCINIC ACID|itaconate

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What are the physical properties of Itaconic acid?

Melting Point 162-164 °C (decomp)
Boiling Point 268 °C
Density 1.632 g/cm³
Flash Point 268°C
Appearance white to light beige crystalline powder
Color White to light beige
Odor Characteristic Odor
Form Crystalline Powder or Crystals
Water Solubility Soluble in water, acetone, methanol, hexane and ethanol. Slightly soluble in benzene, chloroform, carbon disulfide and petroleum ether.
Vapor Pressure 0.0000115 Pa (20 °C)
Refractive Index 1.4980 (estimate)
pH 2 (10g/l, H2O, 20℃)
Log P -0.301 at 20℃

How is Itaconic acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H318 Causes serious eye damage
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H402 Harmful to aquatic life

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.

Which trade and regulatory codes apply to Itaconic acid?

HS Code 29171990
Storage Class 13 - Non Combustible Solids
WGK (Germany) 1
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