Itaconic acid

CAS Number
97-65-4
EC Number
202-586-1
Chemical Formula
C5H6O4
Molecular Weight
130.10 g/mol

Description

Itaconic acid (CAS 97-65-4) is a bio-based unsaturated dicarboxylic acid produced through fungal fermentation, positioning it as a renewable alternative to petrochemical monomers in polymer synthesis. Its reactive double bond and dual carboxylic groups make it a sought-after building block for specialty resins, coatings, and superabsorbent materials used across various industrial sectors.

In polymer and resin manufacturing, it is copolymerized with acrylic acid, styrene, or vinyl acetate to modify adhesion, flexibility, and hydrophilicity in coatings, binders, and pressure-sensitive adhesives. Superabsorbent polymer producers incorporate it to tune water absorption performance in hygiene and agricultural products. In personal care, it functions as a co-monomer in film-forming polymers.

Food and flavor applications use it as an acidulant and flavoring agent, where its mild acidity profile suits beverage and confectionery systems requiring precise pH control and stability. The material is supplied as a white crystalline powder in bags, supersacks, and bulk quantities suited to industrial procurement volumes. Standard commercial grades include technical and FCC specifications.

Purity levels are typically at 99% or above for most applications. Fermentation-derived material dominates the market, and buyers should confirm feedstock origin with suppliers for bio-based claims.

Other Names (Synonyms)

propylenedicarboxylic acid|methylenebutanedioic acid|2-propene-1,2-dicarboxylic acid|2-methylidenebutanedioic acid|2-methylenesuccinic acid|2-methylenebutanedioic acid|METHYLENESUCCINIC ACID|itaconate

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 162-164 °C (decomp)
Boiling Point 268 °C
Density 1.632 g/cm³
Flash Point 268°C
Appearance white to light beige crystalline powder
Color White to light beige
Odor Characteristic Odor
Form Crystalline Powder or Crystals
Water Solubility Soluble in water, acetone, methanol, hexane and ethanol. Slightly soluble in benzene, chloroform, carbon disulfide and petroleum ether.
Vapor Pressure 0.0000115 Pa (20 °C)
Refractive Index 1.4980 (estimate)
pH 2 (10g/l, H2O, 20℃)
Log P -0.301 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H318 Causes serious eye damage
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H402 Harmful to aquatic life

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.

Trade & Regulatory

HS Code 29171990
Storage Class 13 - Non Combustible Solids
WGK (Germany) 1
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