p-toluenesulfonyl isocyanate

CAS Number
4083-64-1
EC Number
223-810-8
Chemical Formula
C8H7NO3S
Molecular Weight
197.21 g/mol
Abbreviation
PTSI

Description

p-Toluenesulfonyl isocyanate (CAS 4083-64-1), commonly known as tosyl isocyanate or PTSI, is a reactive isocyanate reagent used across coatings, adhesives, and polymer systems. It functions primarily as a crosslinking agent and moisture scavenger, reacting with hydroxyl and amine groups to build or stabilize polymer networks in various industrial applications.

In polyurethane coatings and adhesives, PTSI acts as a crosslinker that improves chemical resistance and film hardness without requiring elevated cure temperatures for the final product. Sealant and elastomer formulators use it to scavenge residual moisture from systems sensitive to premature gelation, extending pot life and improving shelf stability during storage.

In textile and leather finishing, it enables durable bonding of functional coatings to fiber substrates by reacting with surface hydroxyl groups to create a strong chemical bond. Plastic and polymer manufacturers incorporate PTSI as a reactive building block in specialty monomers where controlled isocyanate functionality is required for specific material properties.

p-Toluenesulfonyl isocyanate is supplied as a clear to pale yellow liquid. Technical grade is the standard commercial form, with purity specifications typically ranging from 97% upward. Packaging options generally include small reagent quantities through to drum-scale volumes for industrial procurement, ensuring flexibility for both laboratory and large-scale manufacturing needs.

Other Names (Synonyms)

Tosyl isocyanate|4-Methylbenzenesulfonyl isocyanate|p-Toluenesulphonyl isocyanate|Benzenesulfonyl isocyanate, 4-methyl-|Additive ti|H9004FJX6V|p-Toluenesulfonic acid, anhydride with isocyanic acid|PTSI

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 188-189 °C
Boiling Point 75-80 °C @ Press: 0.05-0.1 Torr
Density 3.877 g/cm³ @ Temp: 827 °C
Flash Point >230 °F
Appearance clear liquid
Color Clear colorless to yellow
Odor acrid odor
Form Liquid
Water Solubility reacts
Vapor Pressure 1 mm Hg ( 100 °C)
Refractive Index n 20/D 1.534(lit.)
Log P 0.6 at 30℃

Documentation

Safety & Handling Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS06· Toxic

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H330 Fatal if inhaled

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29309090
UN Number 2206
ADR Class 6.1
Packing Group III
Storage Class 10 - Combustible liquids
WGK (Germany) 1
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