Ethyl tert-butyl ether

CAS Number
637-92-3
EC Number
211-309-7
Chemical Formula
C6H14O
Molecular Weight
102.17 g/mol

Description

Ethyl tert-butyl ether (CAS 637-92-3), commonly known as ETBE, is a fuel oxygenate and blending component produced from bioethanol and isobutylene. It is used primarily to raise the octane rating of gasoline and reduce tailpipe emissions. In fuel blending, ETBE is incorporated into gasoline at regulated concentrations to meet octane specifications and comply with clean fuel mandates across European and Asian markets. Refiners favor it over MTBE in regions where bio-derived content requirements apply.

Its bioethanol origin supports renewable fuel obligations. In solvent applications, it functions as a low-polarity carrier in specialty coatings, extraction processes, and chemical synthesis where controlled evaporation rate and miscibility are relevant. Its low water solubility compared to ethanol also reduces groundwater contamination risk. This is a key procurement consideration in environmentally regulated markets where strict safety and environmental standards are enforced for chemical handling.

ETBE is supplied as a liquid in bulk tanker, ISO container, and drummed formats suited to fuel-grade logistics. Fuel-grade is the primary commercial specification, with purity typically at 99%+ for blending applications. Technical-grade material is available for industrial solvent use, with supply volumes generally tied to refinery or petrochemical production schedules. This ensures a consistent supply chain for large-scale industrial and energy sector operations.

Other Names (Synonyms)

ETBE|tert-Butyl ethyl ether|2-Ethoxy-2-methylpropane|Ethyl tert-butyl oxide|Propane, 2-ethoxy-2-methyl-|Ether, tert-butyl ethyl|Ethyl 1,1-dimethylethyl ether|ETBE (ETHYL TERT.-BUTYL ETHER)

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -94 °C
Boiling Point 72.9 °C @ Press: 750 Torr
Density 0.735 g/cm³ @ Temp: 25 °C; Press: 750 Torr
Flash Point -19 °C
Appearance colourless to light yellow liquid
Color White
Form Powder/Solid
Water Solubility Miscible with alcohol, ethyl ether. Slightly miscible with water.
Vapor Pressure 155 mm Hg ( 25 °C)
Refractive Index n 20/D 1.375(lit.)

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H224 Extremely flammable liquid and vapor
H225 Highly Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Trade & Regulatory

HS Code 29091990
UN Number 1179
ADR Class 3
Packing Group II
WGK (Germany) 1
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