Ethyl tert-butyl ether

CAS Number
637-92-3
EC Number
211-309-7

What is Ethyl tert-butyl ether?

Ethyl tert-butyl ether (CAS 637-92-3), commonly known as ETBE, is a fuel oxygenate and blending component produced from bioethanol and isobutylene.

Where is Ethyl tert-butyl ether used?

  • Gasoline: raises octane rating and reduces tailpipe emissions
  • Fuel blending: incorporated at regulated concentrations to meet octane specifications and comply with clean fuel mandates in European and Asian markets
  • Refiners favor it over MTBE where bio-derived content requirements apply
  • Its bioethanol origin supports renewable fuel obligations
  • Solvent applications: low-polarity carrier in specialty coatings, extraction processes, and chemical synthesis where controlled evaporation rate and miscibility are relevant
  • Its low water solubility compared to ethanol reduces groundwater contamination risk.

Good to know: Its low water solubility compared to ethanol reduces groundwater contamination risk, a key procurement consideration in environmentally regulated markets with strict safety and environmental standards for chemical handling.

Commercial specifications

  • Fuel-grade is the primary commercial specification
  • Purity typically 99%+ for blending applications
  • Technical-grade material available for industrial solvent use
  • Supply volumes generally tied to refinery or petrochemical production schedules

Other Names (Synonyms)

ETBE|tert-Butyl ethyl ether|2-Ethoxy-2-methylpropane|Ethyl tert-butyl oxide|Propane, 2-ethoxy-2-methyl-|Ether, tert-butyl ethyl|Ethyl 1,1-dimethylethyl ether|ETBE (ETHYL TERT.-BUTYL ETHER)

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What are the physical properties of Ethyl tert-butyl ether?

Melting Point -94 °C
Boiling Point 72.9 °C @ Press: 750 Torr
Density 0.735 g/cm³ @ Temp: 25 °C; Press: 750 Torr
Flash Point -19 °C
Appearance colourless to light yellow liquid
Color White
Form Powder/Solid
Water Solubility Miscible with alcohol, ethyl ether. Slightly miscible with water.
Vapor Pressure 155 mm Hg ( 25 °C)
Refractive Index n 20/D 1.375(lit.)

How is Ethyl tert-butyl ether classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H224 Extremely flammable liquid and vapor
H225 Highly Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Ethyl tert-butyl ether?

HS Code 29091990
UN Number 1179
ADR Class 3
Packing Group II
WGK (Germany) 1
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