SoleChem

Dimethyl disulfide

Catalysts & Catalyst Precursors Pharmaceuticals & Healthcare
CAS
624-92-0
EC
210-871-0
Mol. Weight
94.20 g/mol

Description

Dimethyl disulfide (CAS 624-92-0), commonly known as DMDS, is an organosulfur compound used across refining, agriculture, and flavor industries. Methyl disulfide is a recognized alternative name in fragrance and flavor sourcing contexts.

It functions primarily as a sulfiding agent for catalysts, a soil fumigant, and a flavoring ingredient. In petroleum refining, DMDS presulfides hydroprocessing catalysts before startup, activating them efficiently.

This process occurs without requiring hazardous hydrogen sulfide gas handling. Food and flavor manufacturers use it as a FEMA 3536-approved flavoring agent, contributing savory, onion, and cooked-meat notes.

These notes are essential for processed foods and seasonings. In agriculture, it acts as a soil fumigant and nematicide, replacing methyl bromide in pre-plant treatments for high-value crops.

Biotechnology and fermentation applications also employ DMDS as a sulfur source in microbial culture media. This is particularly useful where controlled sulfur supplementation is required for specific growth.

Dimethyl disulfide is supplied as a clear to pale yellow liquid, typically in drum, IBC, and bulk tanker quantities. Food-grade material is available meeting strict industry specifications for safety.

Technical and catalyst-grade material is sourced for refinery and agricultural applications. Purity grades commonly range from 98% to 99%+ depending on the specific end-use requirements of the client.

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Physical Properties

Melting Point -85 °C
Boiling Point 109.8 °C
Density 1.0625 g/cm³ @ Temp: 20 °C
Flash Point 76 °F
Appearance colourless to yellow liquid with a very unpleasant smell
Color Clear yellow
Odor at 0.10 % in propylene glycol. sulfurous vegetable cabbage onion
Form Liquid
Water Solubility <0.1 g/100 mL at 20 ºC
Vapor Pressure 22 mm Hg ( 20 °C)
Refractive Index n 20/D 1.525(lit.)
Log P 1.91 at 20℃

Safety & Handling (Learn More)

Danger GHS02 GHS06 GHS08 GHS09 GHS07
Hazard Statements
H225 Highly Flammable liquid and vapor
H301 Toxic if swallowed
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H320 Causes eye irritation
H330 Fatal if inhaled
H331 Toxic if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29309070
UN Number 2381
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 2

Documentation

Other Names

Sulfa-hitech 0382|Sulfa-hitech|Methyl disulfide|DMDS|Disulfide dimethyl|2,3-dithiabutane|(methyldithio)methane|(methyldisulfanyl)methane

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