Sodium benzoate

CAS Number
532-32-1
EC Number
208-534-8
E Number
E211
FEMA Number
FEMA 3025

What is Sodium benzoate?

Sodium benzoate (CAS 532-32-1), also known as E211, is the sodium salt of benzoic acid used as a broad-spectrum preservative in food, pharmaceutical, and personal care industries.

Where is Sodium benzoate used?

  • Food and beverage: shelf-life extension in carbonated drinks, fruit juices, condiments, and pickled products
  • Pharmaceuticals: preservative in oral liquids and syrups
  • Topical preparations requiring low-pH stability
  • Personal care: preservative in shampoos, lotions, and wet wipes
  • Industrial process fluids: pH buffer and corrosion inhibitor
  • It inhibits microbial growth in acidic environments.
  • Can be combined with other preservatives such as sodium nitrite (E250) or potassium sorbate (E202) for a synergistic antimicrobial effect, allowing a lower dose.
  • Used in medications as an anti-fermentation additive and as a tableting lubricant for drugs.
  • Can also be added to natural cosmetics.

Formulation notes

  • In Türkiye, allowed at a maximum of 0.1% in food applications.
  • In rinse-off cosmetic products, reaches a concentration of 2.5%.
  • All oral care products can contain 1.7% sodium benzoate.
  • Should not be mixed with vitamin C, as this combination produces benzene, a toxic compound.

Typical specification

  • Available in a fine powder form.

Regulatory status

  • Listed under HS code 2916.31.00.

Storage, packaging and handling

  • Slightly hygroscopic.
  • Commonly packed in 25 kg bags.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

E211|Benzoic acid, sodium salt|Sobenate|Antimol|Benzoate sodium|Benzoate of soda|Natrium benzoicum|Benzoic acid, sodium salt (1:1)

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What are the physical properties of Sodium benzoate?

Melting Point >300 °C
Density 0.100552 g/cm³ @ Temp: 15 °C
Flash Point >100°C
Appearance Sodium benzoate is a white crystalline solid. It is odorless and nonflammable
Color White
Odor odorless
Form Crystals, Granules, Flakes or Crystalline Powder
Water Solubility soluble
Vapor Pressure 0Pa at 20℃
pH 7.0-8.5 (25℃, 1M in H2O)
Log P 1.88

How is Sodium benzoate classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H319 Causes serious eye irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264+P265 Wash … thoroughly after handling.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Which trade and regulatory codes apply to Sodium benzoate?

HS Code 29163100
WGK (Germany) 1
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