Benzaldehyde

CAS Number
100-52-7
EC Number
202-860-4
FEMA Number
FEMA 2127

What is Benzaldehyde?

Benzaldehyde (CAS 100-52-7), also known as benzoic aldehyde, is the simplest aromatic aldehyde and a primary aroma chemical recognized under FEMA 2127; it delivers the characteristic bitter almond scent.

Where is Benzaldehyde used?

  • Pharmaceutical synthesis: key intermediate for active ingredients including ampicillin and other semi-synthetic penicillins
  • Food and beverage: flavoring agent imparting almond, cherry, and marzipan profiles in confectionery, baked goods, and liqueurs
  • Polymer chemistry: monomer or chain-transfer agent in resin and coating formulations
  • Personal care: perfume compounds and functional fragrance blends with a sharp, almond-floral note
  • It also serves as a reactive building block for fine chemical production.

Good to know: Food-grade material meeting FCC specifications is standard for flavor applications, while technical-grade product serves industrial synthesis and polymer uses. Natural benzaldehyde, derived from bitter almond or stone fruit processing, is a distinct commercial grade commanding a premium in flavor and fragrance markets.

Commercial specifications

  • Clear liquid in drum, IBC, and bulk quantities
  • Natural grade: derived from bitter almond or stone fruit processing, high purity

Other Names (Synonyms)

benzoyl hydride|benzoic aldehyde|benzoic acid aldehyde|benzene methylal|benzene carboxaldehyde|benzene carbaldehyde|BEZ|Benzaldehyde FFC

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What are the physical properties of Benzaldehyde?

Melting Point -26 °C
Boiling Point 179 °C
Density 1.050 g/cm³ @ Temp: 15 °C
Flash Point 145 °F
Appearance Benzaldehyde is a clear to yellowish liquid with an almond odor. The Odor Threshold is 0.042 ppm.
Color Pale yellow
Odor Like almonds.
Form neat
Water Solubility <0.01 g/100 mL at 19.5 ºC
Vapor Pressure 4 mm Hg ( 45 °C)
Refractive Index n 20/D 1.545(lit.)
pH 5.9 (1g/l, H2O)
Log P 1.4 at 25℃

How is Benzaldehyde classified and handled safely? Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H227 Combustible liquid
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Which trade and regulatory codes apply to Benzaldehyde?

HS Code 29122100
UN Number 1990
ADR Class 9
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 1
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