Potassium ferrocyanide

CAS Number
13943-58-3
EC Number
237-722-2
E Number
E536

What is Potassium ferrocyanide?

Potassium ferrocyanide (CAS 13943-58-3), also known commercially as E536 and tetrapotassium hexacyanoferrate, is an inorganic iron-cyanide salt.

Where is Potassium ferrocyanide used?

  • Food production: anti-caking additive in table salt and salt substitutes, preventing clumping during storage and packaging
  • Metal processing: selective precipitant of heavy metals, particularly copper and zinc, from process streams and wastewater
  • Winemaking: fining agent that removes excess copper and iron ions
  • Textile and leather dyeing: reducing auxiliary and fixative
  • Blue pigment formulations, including Prussian blue production
  • It is also used in industrial separation processes.

Good to know: Food-grade material meets E536 specification and purity requirements for edible salt applications; technical grade is for industrial water treatment, mining, and dyeing where food compliance is not required.

Commercial specifications

  • Food-grade to E536 specification
  • Purity requirements for edible salt applications

Other Names (Synonyms)

tetrapotassium hexacyanoferrate|K4[Fe(CN)6]|Tetrapotassium hexacyanoferrate(II)|RefChem:867813|lambda6-iron(6+) ion tetrapotassium hexakis(iminomethanide)|Potassium (Oc-6-11)-Hexakis(Cyano-Kappa-C)Ferrate(4-)(4:1)|Ferrate(4-), hexakis(cyano-κC)-, potassium (1:4), (OC-6-11)-|E536

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What are the physical properties of Potassium ferrocyanide?

Melting Point 70 °C
Boiling Point 104.2 °C
Density 1.886 g/cm³
Appearance Lemon-yellow crystals or powder; mild saline taste. Effloresces on exposure to air; soluble in water; insoluble in alcohol.
Form yellow granules (rough estimate)
Water Solubility 254g/L at 20℃

How is Potassium ferrocyanide classified and handled safely? Learn More

GHS09· Environmental Hazard

Hazard Statements

H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.
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