SoleChem

Potassium ferrocyanide

CAS
13943-58-3
EC
237-722-2
Mol. Weight
368.34 g/mol

Description

Potassium ferrocyanide (CAS 13943-58-3), also known commercially as E536 and tetrapotassium hexacyanoferrate, is an inorganic iron-cyanide salt used across food processing, metal treatment, and industrial separation processes.

It functions primarily as an anti-caking agent, chelating agent, and selective precipitant depending on the application sector. In food production, E536 is approved as an anti-caking additive in table salt and salt substitutes.

This additive prevents clumping during storage and packaging. Metal processing operations use it to selectively precipitate heavy metals, particularly copper and zinc, from process streams and wastewater, supporting both recovery and effluent compliance.

In winemaking, it is applied as a fining agent to remove excess copper and iron ions that would otherwise cause haze or off-flavors. Textile and leather dyeing processes rely on it as a reducing auxiliary and fixative.

It is also used in blue pigment formulations, including Prussian blue production. Potassium ferrocyanide is supplied as a yellow crystalline powder or granules. Food-grade material is available to E536 specification.

This material meets purity requirements for use in edible salt applications. Technical grade is supplied for industrial water treatment, mining, and dyeing applications where food compliance is not required.

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Physical Properties

Melting Point 70 °C
Boiling Point 104.2 °C
Density 1.886 g/cm³
Appearance Lemon-yellow crystals or powder; mild saline taste. Effloresces on exposure to air; soluble in water; insoluble in alcohol.
Form yellow granules (rough estimate)
Water Solubility 254g/L at 20℃

Safety & Handling (Learn More)

GHS09
Hazard Statements
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
Precautionary Statements
P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.

Documentation

Other Names

tetrapotassium hexacyanoferrate|K4[Fe(CN)6]|Tetrapotassium hexacyanoferrate(II)|RefChem:867813|lambda6-iron(6+) ion tetrapotassium hexakis(iminomethanide)|Potassium (Oc-6-11)-Hexakis(Cyano-Kappa-C)Ferrate(4-)(4:1)|Ferrate(4-), hexakis(cyano-κC)-, potassium (1:4), (OC-6-11)-|E536

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