Lithium bromide

CAS Number
7550-35-8
EC Number
231-439-8
Abbreviation
LiBr

What is Lithium bromide?

Lithium bromide (CAS 7550-35-8), commonly abbreviated as LiBr, is an inorganic salt used across industrial refrigeration, pharmaceutical manufacturing, and life sciences.

Where is Lithium bromide used?

  • Industrial refrigeration: absorption refrigerant and desiccant in gas drying systems
  • Commercial HVAC and industrial cooling: absorbent fluid in absorption chiller systems
  • Chemical synthesis: reagent whose strong affinity for water vapor drives the refrigeration cycle without mechanical compression
  • Pharmaceutical manufacturing: reagent in synthesis and buffering agent in select formulations requiring controlled ionic conditions
  • Biotechnology and life sciences: solutions precipitate and purify RNA
  • Water treatment: biocide and pH-regulation contexts where lithium-based chemistry is specified
  • Used in organic synthesis to facilitate carbon-carbon bond formation and catalyze the creation of cyclic compounds.
  • Converts alcohols into alkyl bromides.
  • An essential reagent in aldol condensations.
  • High-purity grades serve as standard reference material or auxiliary component in certain analytical tests.
  • In lithium bromide refrigerators, lithium chromate is a common corrosion inhibitor.

Formulation notes

  • Aqueous solutions are corrosive to metals; use with corrosion inhibitors is recommended.
  • Releases heat when mixed with water.

Typical specification

  • Available in an anhydrous form.
  • Hydrate offered in a Suprapur grade with a purity of 99.95%.

Regulatory status

  • Carries hazard statement H302 (harmful if swallowed).
  • Waste directive 2008/98/EC must be observed for disposal.

Storage, packaging and handling

  • When working with lithium bromide, moisture control must be ensured and containers must always be kept tightly closed.
  • Each drum contains a net content of 30 kg, 300 kg, or 1500 kg, and can be packed according to customer specifications.

Frequently asked questions about Lithium bromide

What role does octanol play in lithium bromide solution?
Octanol is widely used as the surfactant in lithium bromide solution to improve the absorption effect of the absorber and the condensation effect of the condenser.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

lithium monobromide|Lithium bromide (LiBr)|LITHIUM BROMATUM|864G646I84|RefChem:55513|LiBr

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What are the physical properties of Lithium bromide?

Melting Point 547 °C
Boiling Point 133 °C @ Press: Atm pressure
Density 3.464 g/cm³ (solid)
Flash Point 1265°C
Appearance White powder
Color White
Odor odorless
Form powder
Water Solubility 61 g/100 mL (25 º C)
Vapor Pressure 1 hPa ( 748 °C)
pH 7 (20°C, 10g/L)
Log P -0.37 at 25℃

How is Lithium bromide classified and handled safely? Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H371 May cause damage to organs
H373 May causes damage to organs through prolonged or repeated exposure

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Lithium bromide?

HS Code 28275900
Storage Class 13 - Non Combustible Solids
WGK (Germany) 2
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