SoleChem

Pyrogallol

CAS
87-66-1
EC
201-762-9
Mol. Weight
126.11 g/mol

Description

Pyrogallol (CAS 87-66-1), also sold under the trade names Piral, Fourrine PG, and Fourrine 85, is a trihydric phenol used industrially as an antioxidant and reducing agent.

It serves as a fixative across pharmaceutical, cosmetic, and specialty chemical applications. Its strong reducing capacity makes it a functional ingredient in formulations requiring controlled oxidation.

In hair dye and cosmetic colorant systems, it acts as an oxidative dye coupler, contributing to brown and black shades in professional and consumer hair color products for the beauty industry.

Pharmaceutical manufacturers use it as an intermediate in the synthesis of active compounds and as an antioxidant stabilizer in sensitive formulations to ensure long-term product stability and efficacy.

In photographic and analytical chemistry applications, it functions as a developing agent and oxygen-absorbing reagent. Food-contact and packaging applications also draw on its antioxidant properties.

These properties protect against oxidative degradation in material formulations. The product is supplied as a white to off-white crystalline powder for various industrial and laboratory uses.

Technical and reagent-grade specifications are standard across the market, with pharmaceutical-grade material available to meet compendial purity requirements for high-specification manufacturing projects.

Packaging typically ranges from kilogram-scale laboratory quantities to multi-hundred kilogram bulk orders depending on grade and supplier requirements for global distribution and logistics.

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Physical Properties

Melting Point 133 °C
Boiling Point 309 °C
Density 1.453 g/cm³ @ Temp: 4 °C
Flash Point >230 °F
Appearance white crystalline solid
Color White
Form Very Fine Crystalline Powder
Water Solubility 400 g/L (25 ºC)
Vapor Pressure 10 mm Hg ( 167.7 °C)
Refractive Index n 20/D 1.387
pH 4-5 (50g/l, H2O, 20℃)
Log P -0.47

Safety & Handling (Learn More)

Warning GHS07 GHS08
Hazard Statements
H302 Harmful if swallowed
H312 Harmful in contact with skin
H313 May be harmful in contact with skin
H315 Causes skin irritation
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H370 Causes damage to organs
H371 May cause damage to organs
H412 Harmful to aquatic life with long lasting effects
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29072200
UN Number 2811
ADR Class 6.1
Packing Group III
Storage Class 11 - Combustible Solids
WGK (Germany) 3

Documentation

Other Names

Piral|Fourrine PG|Fourrine 85|Fouramine Brown AP|Fouramine base ap|C.I. Oxidation Base 32|Benzene-1,2,3-triol|2,3-Dihydroxyphenol

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