Pyrogallol

CAS Number
87-66-1
EC Number
201-762-9
Chemical Formula
C6H6O3
Molecular Weight
126.11 g/mol

Description

Pyrogallol (CAS 87-66-1), also sold under the trade names Piral, Fourrine PG, and Fourrine 85, is a trihydric phenol used industrially as an antioxidant and reducing agent. It serves as a fixative across pharmaceutical, cosmetic, and specialty chemical applications. Its strong reducing capacity makes it a functional ingredient in formulations requiring controlled oxidation.

In hair dye and cosmetic colorant systems, it acts as an oxidative dye coupler, contributing to brown and black shades in professional and consumer hair color products for the beauty industry. Pharmaceutical manufacturers use it as an intermediate in the synthesis of active compounds and as an antioxidant stabilizer in sensitive formulations to ensure long-term product stability and efficacy.

In photographic and analytical chemistry applications, it functions as a developing agent and oxygen-absorbing reagent. Food-contact and packaging applications also draw on its antioxidant properties. These properties protect against oxidative degradation in material formulations. The product is supplied as a white to off-white crystalline powder for various industrial and laboratory uses.

Technical and reagent-grade specifications are standard across the market, with pharmaceutical-grade material available to meet compendial purity requirements for high-specification manufacturing projects. Packaging typically ranges from kilogram-scale laboratory quantities to multi-hundred kilogram bulk orders depending on grade and supplier requirements for global distribution and logistics.

Other Names (Synonyms)

Piral|Fourrine PG|Fourrine 85|Fouramine Brown AP|Fouramine base ap|C.I. Oxidation Base 32|Benzene-1,2,3-triol|2,3-Dihydroxyphenol

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 133 °C
Boiling Point 309 °C
Density 1.453 g/cm³ @ Temp: 4 °C
Flash Point >230 °F
Appearance white crystalline solid
Color White
Form Very Fine Crystalline Powder
Water Solubility 400 g/L (25 ºC)
Vapor Pressure 10 mm Hg ( 167.7 °C)
Refractive Index n 20/D 1.387
pH 4-5 (50g/l, H2O, 20℃)
Log P -0.47

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H313 May be harmful in contact with skin
H315 Causes skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29072200
UN Number 2811
ADR Class 6.1
Packing Group III
Storage Class 11 - Combustible Solids
WGK (Germany) 3
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